Popular Scientific Recreations: in Natural Philosphy, Astronomy, Geology, Chemistry, etc., etc., etc.Tissandier, Gaston
Science
Popular Scientific Recreations: in Natural Philosphy, Astronomy, Geology, Chemistry, etc., etc., etc.
Tissandier, Gaston
Scientific recreations
In the accompanying illustration of the Galvanic Pile a disc of copper
is at the bottom and a disc of zinc at the top. The latter, P,
is the positive pole; the former, N, the negative. When the
wires are united the current is closed, and no sign of disturbance can
be detected, although the action, of course, is proceeding within the
pile. The opposite kinds of electricity neutralize each other, and if a
continuous supply were not kept up the electricity would disappear; but
as it is, a powerful current is obtained, and if the wire be divided a
spark will be observed.
[Illustration: Fig. 222.—Bunsen Battery.]
There are many forms of galvanic batteries. The Trough Battery or
Cruickshank has been mentioned. There is Wollaston’s Pile, Bunsen’s
Battery, Grove’s Battery, and Daniell’s, called the “Constant” Battery.
In this last a porous earthenware cell is placed within a cylinder
of copper; in the cell a rod of zinc is inserted, the cell being
filled with diluted sulphuric acid,—one part of acid to ten parts of
water,—and in the outer cylinder is a solution of sulphate of copper.
[Illustration: Fig. 223.—Daniell’s Battery.]
[Illustration: Fig. 224.—Grove’s Battery.]
The cut above illustrates Daniell’s Battery (fig. 223) with connectors.
In _Bunsen’s Battery_ (or the Zinc-Carbon Battery), which is very like
the “Daniell” arrangement, as will be seen from the plates (figs. 222,
223), the porous cell has a prism of carbon immersed in it, and is
apparently a modification of the powerful “Grove” Battery (fig. 224).
This consists of slips of platinum, _h_, placed in porous cells, _g_,
each cell being surrounded by a glass cylinder. The outer (glass) cells
are filled, or nearly filled, with diluted sulphuric acid; nitric
acid is used in the porous cells, and a platinum plate inserted. The
chemical action of the Grove cell is thus explained by Professor
Stewart: “The zinc dissolves in the dilute sulphuric acid, and during
this process hydrogen gas is given off. But this hydrogen does not
rise up in the shape of bubbles; it finds its way into the porous
vessel which contains the strong nitric acid. It there decomposes the
acid, taking some oxygen to itself, so as to become water (hydrogen
and oxygen forming water), and thereby turning the nitric into nitrous
acid, which shows its presence by strong orange-coloured fumes.” By
this decomposition of the nitric acid the polarization of the platinum
(due to hydrogen) is avoided. The porous cell, while keeping the
liquids apart, does not interfere with the chemical action.
A great number of cells are used in the Grove Battery; perhaps even a
hundred may be employed.
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