Popular Scientific Recreations: in Natural Philosphy, Astronomy, Geology, Chemistry, etc., etc., etc.Tissandier, Gaston
Science
Popular Scientific Recreations: in Natural Philosphy, Astronomy, Geology, Chemistry, etc., etc., etc.
Tissandier, Gaston
Scientific recreations
Sulphate of soda is very soluble in water, and at a temperature of
thirty-three (Centigr.) water can dissolve it in the greatest degree.
If we pour a layer of oil on a solution saturated with Glauber’s
salts, and let it stand, it will not produce crystals; but if we
thrust a glass rod through the oil into contact with the solution,
crystallization will be instantaneous. This singular phenomenon becomes
even more striking when we put the warm concentrated solution into a
slender glass tube, A B, which we close after having driven out the
air by the bubbling of the liquid (fig. 306). When the tube has been
closed, the crystals of sulphate of soda will not form, even with the
temperature at zero; nevertheless the salts, being less soluble cold
than hot, are found in the fluid in a proportion ten times larger than
they would contain under ordinary conditions. If the end of the tube be
broken the salt will crystallize immediately. We will describe another
experiment, but little known and very remarkable, which exhibits in a
striking manner the process of instantaneous crystallizations. Let one
hundred and fifty parts of hyposulphite of soda be dissolved in fifteen
parts of water, and the solution slowly poured into a test-glass,
previously warmed by means of boiling water, until the vessel is about
half-full. One hundred parts of acetate of soda is then dissolved in
fifteen parts of water, and poured slowly into the first solution,
so that they form two layers perfectly distinct from each other. The
two solutions are then covered with a little boiling water, which,
however is not represented in our illustration. After it has been left
to stand and cool slowly, we have two solutions of hyposulphite of
soda and acetate of soda superposed on each other. A thread, at the
end of which is fixed a small crystal of hyposulphite of soda, is then
lowered into the test-glass; the crystal passes through the solution of
acetate without disturbing it, but it has scarcely reached the lower
solution of hyposulphite than the salt crystallizes instantaneously.
(_See_ the test-glass on the left of fig. 307.) We then lower into the
upper solution a crystal of acetate of soda, suspended from another
thread. This salt then crystallizes also. (_See_ experiment glass on
the right of fig. 307.) This very successful experiment is one of the
most remarkable belonging to the subject of instantaneous crystals.
The successive appearance of crystals of hyposulphite of soda, which
take the form of large, rhomboidal prisms, terminating at the two
extremities with an oblique surface, and the crystals of acetate of
soda, which have the appearance of rhomboidal, oblique prisms, cannot
fail to strike the attention and excite the interest of those who are
not initiated into these kinds of experiments.
[Illustration: Fig. 307.—Experiment of instantaneous crystallization.]
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