(180.) The surest and best characteristic of a well-founded and
extensive induction, however, is when verifications of it spring up,
as it were, spontaneously, into notice, from quarters where they might
be least expected, or even among instances of that very kind which
were at first considered hostile to them. Evidence of this kind is
irresistible, and compels assent with a weight which scarcely any other
possesses. To give an example: M. Mitscherlich had announced a law to
this effect--_that_ the chemical elements of which all bodies consist
are susceptible of being classified in distinct groups, which he termed
_isomorphous_ groups; and _that_ these groups are so related, that
when similar combinations are formed of individuals belonging to two,
three, or more of them, such combinations will crystallize in the same
geometrical forms. To this curious and important law there appeared
a remarkable exception. According to professor Mitscherlich, the
arsenic and phosphoric acids _are_ similar combinations coming under
the meaning of his law, and their combinations with soda and water,
forming the salts known to chemists under the names of arseniate and
phosphate of soda, ought, if the law were general, to crystallize in
identical shapes. The fact, however, was understood to be otherwise.
But lately, Mr. Clarke, a British chemist, having examined the two
salts attentively, ascertained the fact that their compositions
deviate essentially from that similarity which M. Mitscherlich’s law
requires; and that, therefore, the exception in question disappears.
This was something: but, pursuing the subject further, the same
ingenious enquirer happily succeeded in producing a _new_ phosphate of
soda, differing from that generally known in containing a different
proportion of water, and agreeing in composition exactly with the
arseniate. The crystals of this new salt, when examined, were found by
him to be precisely identical in form with those of the arseniate: thus
verifying, in a most striking and totally unexpected manner, the law in
question, or, as it is called, the law of isomorphism.
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