(374.) Though the original pile of Volta was feeble compared to those
gigantic combinations which were afterwards produced, it sufficed,
however, to exhibit electricity under a very different aspect from any
thing which had gone before, and to bring into view those peculiar
modifications in its action which Dr. Wollaston was the first to
render a satisfactory account of, by referring them to an increase
of _quantity_, accompanied with a diminution of _intensity_ in the
supply afforded. The discovery had not long been made public, and
the instrument in the hands of chemists and electricians, before it
was ascertained that the electric current, transmitted by it through
conducting liquids, produces in them chemical decompositions. This
capital discovery appears to have been made, in the first instance, by
Messrs. Nicholson and Carlisle, who observed the decomposition of water
so produced. It was speedily followed up by the still more important
one of Berzelius and Hisinger, who ascertained it as a general law,
that, in all the decompositions so effected, the acids and oxygen
become transferred to, and accumulated around, the positive,--and
hydrogen, metals, and alkalies round the negative, pole of a Voltaic
circuit; being transferred in an invisible, and, as it were, a latent
or torpid state, by the action of the electric current, through
considerable spaces, and even through large quantities of water or
other liquids, again to re-appear with all their properties at their
appropriate resting-places.
(375.) It was in this state of things that the subject was taken up
by Davy, who, seeing that the strongest chemical affinities were thus
readily subverted by the decomposing action of the pile, conceived
the happy idea of bringing to bear the intense power of the enormous
batteries of the Royal Institution on those substances which, though
strongly suspected to be compounds, had resisted all attempts to
decompose them--the alkalies and earths. They yielded to the force
applied, and a total revolution was thus effected in chemistry; not so
much by the introduction of the new elements thus brought to light, as
by the mode of conceiving the nature of chemical affinity, which from
that time has been regarded (as Davy broadly laid it down, in a theory
which was readily adopted by the most eminent chemists, and by none
more readily than by Berzelius himself,) as entirely due to electric
attractions and repulsions, those bodies combining most intimately
whose particles are habitually in a state of the most powerful
electrical antagonism, and dispossessing each other, according to the
amount of their difference in this respect.
Public-domain text, read in full here on John Shaqi.
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