As Way had succeeded in producing an artificial hydrated silicate
possessing absorptive properties, Eichorn[88] thought of trying natural
hydrated silicates or zeolites and found that they exhibited the same
power as Way’s artificial preparation. It has also been shown by
Biedermann,[89] Rautlenberg,[90] and Heiden[91] that the absorptive
power bears a close relation to the amount of soluble silicates present.
In view of these facts it is now generally accepted that the absorption
of salts of the alkalies, accompanied by the change of base, is due
chiefly to the presence of decomposed zeolite minerals in the soil.
Besides the purely chemical absorption of salts by the soil, we have a
physical absorption of various substances similar to the action of
charcoal when used as a filter.
=127. Conclusions of Armsby.=—The data connected with the absorption of
bases by a soil have also been reviewed by Armsby.[92] He shows that the
absorption is accompanied by a chemical reaction between the salt whose
base is absorbed and some constituent of the soil, and this change seems
to be due particularly to certain zeolitic silicates, although Liebig
and others were disposed to credit this absorption largely to physical
causes.
Knop advances the idea that the soil has the power of disintegrating
salts in the presence of some substances like calcium carbonate which
can unite with the acid. In experiments made with hydrous silicates it
was shown that the absorption resembled in all cases like phenomena in
the soil; hence the supposition already advanced in regard to the
influence of such silicates is doubtless true.
In respect of absorption in general, the following conclusions were
reached:
1. The absorption of combined bases by the soil consists in an exchange
of bases between the salt and the hydrous silicates of the soil.
2. This exchange, which is primarily chemical, is only partial, its
extent varying
(a) with the concentration of the solution, and
(b) with the ratio between the volume of the solution and the quality of
soil used.
3. The cause of these variations is probably the action of mass or the
tendency of resulting compounds to re-form the original bodies, the
absorption actually found in any case marking the point where the two
forces are in equilibrium.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account