It will be seen that there was no absorption in the case of the nitrate,
while with each of the other salts there was quite a marked absorption.
It will also be noticed that the percentages of absorption are not very
different, and especially is this true of the potassium and ammonium
salts, the P₂O₅ being somewhat higher. Whether this fact is merely an
accidental occurrence or is due to the law of combination by equivalents
could hardly be predicted from the single soil experimented upon; but
taking into consideration the possibility of difference in solubility of
the resulting compounds in the saline solutions used, and of other
varying conditions, the percentages are evidently not far enough apart
to exclude the possibility of the bases uniting in equivalent
proportions.
=138. Preparation of Salts for Absorption.=—The salts employed in the
foregoing determinations are conveniently prepared, in fractional normal
strength.
In grams per liter the following quantities in grams are recommended,
_viz._, 5.35 g NH₄Cl; 10.11 g KNO₃; 16.40 g Ca(NO₃)₂; 24.60 g MgSO₄ +
7H₂O; 23.4 g CaH₄(PO₄)₂, etc.
The ammonium chlorid, potassium nitrate and magnesium sulfate can be
weighed as chemically pure salts and the standard solution be directly
made up. Calcium nitrate is so hygroscopic that a stronger solution must
be made up, the calcium determined and the proper volume taken and
diluted to one liter.
Monocalcium phosphate is prepared as follows:
A solution of sodium phosphate is treated with glacial acetic acid and
precipitated with a solution of calcium chlorid. It is then washed with
water until all chlorin is removed. The fresh precipitate is saturated
with pure, cold phosphoric acid of known strength. After filtering the
solution is placed in a warm room and left for two or three weeks until
crystallization takes place.
The crystals are pressed between blotting papers and finally dried over
sulfuric acid and washed with water-free ether, and again dried. Since
this salt is decomposed in strong solutions it should be used only in
one hundredth normal strength, viz., 2.34 grams per liter.
POROSITY AND ITS RELATIONS TO MOISTURE.
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