=169. Method of Estimating Surface Tension.=—The determination of
surface tension is made by measuring the rise of the liquid in a
capillary tube. A short piece of thermometer tubing is used, the
diameter of the bore being determined by careful microscopic
measurements with a micrometer eyepiece. The diameter of the tube should
be about 0.5578 millimeter. The tube is very thoroughly cleaned after
each observation, or set of observations, with a strong caustic potash
solution, and, after washing, is allowed to stand for some time in a
saturated solution of potassium bichromate in strong sulfuric acid. The
height of the rise in the capillary tube is measured with a
cathetometer.
The following formula is used for the calculation of the results:
T = (_h d_ ω)/(4 cos. _a_)
Where T is the surface tension, _d_ is the diameter of the tube in
centimeters; _h_ the height to which the liquid rises in the capillary
tube in centimeters; ω is the specific gravity of the solution; and 4
cos. _a_ refers to the angle of the liquid with the sides of the glass
tube. For a tube of the size given above, 5° 24′ is the value of this
edge angle. In regard to saline solutions, Quincke[117] says, that the
edge angle appears to increase a little with augmenting concentration of
the saline solution, but otherwise to differ only inconsiderably from
the edge angle of pure water.
=170. Effect of the Solutions on Surface Tension.=—The mineral
fertilizers, as a rule, increase the surface tension of water, while
organic matters in solution decrease it. But it must not be forgotten in
this connection that but little of the organic matter in the fertilizers
employed for the experiment passes into solution. Moreover, with these
substances, the accuracy of the work is impaired somewhat by the
increased viscosity. In general, the results of the experiment are in
harmony with the well-known effect of magnesium, sodium, and potassium
chlorids, and sodium nitrate, to make the soil more moist in dry
weather, and the opposite effect produced by the application of organic
matter.
=171. Method of Preparing Soil Extracts.=—The soil extracts used in
determining the surface tension, as given in the above table, are
prepared as follows:
Ten grams of the soil are rubbed up with fifteen to twenty cubic
centimeters of distilled water and allowed to stand for twenty-four
hours with frequent stirring. Any fine particles not removable by a
filter are neglected, although they may give a turbid appearance to the
solution.
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