collected as above will not diffuse in water it may be washed with water
and its weight directly obtained. An excess of iron in clay will usually
allow of the above treatment.
=228. Properties of Pure Clay.=—The percentage of pure clay as obtained
by the procedure described is about seventy-five in the finest natural
clays, forty-five in heavy clay soils, and fifteen in ordinary loamy
soils. When freshly precipitated by brine it is gelatinous resembling a
mixed precipitate of iron and aluminum oxids. Its volume greatly
contracts on drying, clinging tenaciously to the filter, from which it
may be freed by moistening. On drying, it becomes hard, infriable, and
often resonant. It usually possesses a dark brown tint due to iron oxid.
Under the action of water it swells up like glue, the more slowly as the
percentage of iron is greater. In the dry state it adheres to the tongue
with great tenacity. According to Whitney the finest particles of
colloidal clay have a diameter of 0.0001 millimeter. With a magnifying
power of 350 diameters, however, Hilgard states that no particles can be
discerned.
=229. Chemical Nature of the Fine Clay.=—The fine particles separated as
above consist essentially of hydrous aluminum silicate or kaolinite. It
doubtless contains, however, other colloids or hydrogels whose
absorptive powers are similar to those of clay. It appears also to
contain sometimes free aluminum hydroxid, and colloidal ferric hydroxid,
and amorphous zeolitic compounds.
While the most careful mechanical separation can give at best only
approximately the really plastic kaolinite substance, yet it is far
closer than that attained by determination of total alumina with boiling
sulfuric acid. By the latter treatment all the lime-kaolinite particles
are decomposed and the method does not lead to even an approximate
estimate of the soil’s plasticity.
=230. Separation of the Fine Sediments.=—The sediments remaining after
the separation of the clay and fine silt are ready for separation in the
churn elutriator. The apparatus mounted, as already described, is
brought into use by beginning with a low velocity of the water in the
upright tube. The rate of flow should be set at from 0.25 millimeter to
0.50 millimeter per second, and the churn put in motion.
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