_Phosphorus._—When a mineral fragment containing phosphorus is treated
according to the usual analytical methods for securing the ammonium
magnesium phosphate, crystals are obtained of the form shown in Figs. 54
and 55. A phosphatic fragment of silt may be identified when soluble by
treatment with nitric acid and ammonium molybdate. On slowly drying,
rhombohedral crystals are produced, yellow by reflected, and green by
transmitted light. Their form is shown in Fig. 56.
=260. Petrographic Examination of Silt Particles.=—The larger silt
particles and the minute fragments of minerals in the soil can best be
studied in thin sections. For this purpose the following plan, proposed
by Thoulet, may be used. Mix the soil minerals in considerable
proportion—Thoulet recommends ten per cent, but a greater percentage is
often better—with zinc oxid and make into a paste with sodium silicate.
The paste should be worked to the consistence of putty and then rolled
into little tablets about one-eighth of an inch thick and an inch in
diameter. After drying a day or two without heating, the tablets become
hard enough to mount and grind like rock sections. These tablets are
mounted in Canada balsam on glass slides and ground as thin as possible
with fine emery on the turn-table or glass plate, as rock sections are
treated. As these tablets are not as strong as rock sections usually
are, they require care in this treatment. Some of the grains also are
apt to be torn out in the process of grinding and to compensate for this
loss a number of slides should be prepared with each lot of soil
minerals. When this operation has been successful, the optical
properties of the various minerals can be studied as in rock sections.
As the iron oxid contained in the soils obscures the transparency of the
minerals, it is well to treat a portion of the material under
examination with hot hydrochloric acid for a short time to remove this
oxid and then prepare slides with the cleansed material and compare
results with the untreated. As the acid will dissolve phosphates and
carbonates, and will partly or wholly decompose some other minerals, the
operator must be guided by his judgment in its use.
=261. Machine for Making Mineral Sections.=—A convenient apparatus for
this purpose has been described by Williams[167] and is represented in
Fig. 57. It is supported on a substantial table provided underneath with
electric batteries and a motor for driving the cutting disks seen on the
top. The table is three feet six inches square and two feet nine inches
high.
[Illustration:
FIGURE 57.
MACHINE FOR MAKING MINERAL SECTIONS.
]
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