The absorption tube consists of a =ᥩ= shaped wide glass tube, both ends
of which are supplied with small glass tubes sealed upon the end of the
=ᥩ= tube, and those are furnished with tightly-ground glass stop-cocks.
Above these stop-cocks these small tubes are bent in opposite directions
at right angles. On the bend of the =ᥩ= is sealed another tube which is
furnished with a ground glass stopper. Through this opening the =ᥩ= tube
can be filled with the sample of soil. When the tube is filled, the
glass stopper inserted, and the two stop-cocks on the small tubes
closed, the contents of the tube are completely excluded from the
external atmosphere. Many of these tubes can be used at once so as to
hasten the progress of the work.
The tubes after being filled are placed in a drying oven with the
stop-cocks open. The stop-cocks are then closed before the tubes are
removed, when they are placed in a desiccator for cooling preparatory to
weighing. The weighed tubes are held in a tin box which can be placed in
a water-bath which is kept at a given temperature by means of a
thermostat. The top of the tin box should be hinged and made of a thick
non-conducting material so as to prevent any rapid change of temperature
within. On the inner side of the box a small thin-walled glass tube is
carried around four times. One end of this tube passes through an
opening in the side of the box by means of which it can be connected
with the gas apparatus outside. The other end of it is connected
directly with the absorption tubes.
The absorption tubes are so connected among themselves that when ammonia
or carbon dioxid is employed the gas passes through one of the tubes
before it can reach the next, and so on. For experiments with water-gas,
however, that is, air charged with aqueous vapor, the arrangement must
be different. While in the case of ammonia and carbon dioxid the
composition of the gas is not changed by passing through the samples of
soil, the case is quite different when air charged with aqueous vapor
passes through. In the latter case the amount of aqueous vapor in the
air would be notably lessened in passing from sample to sample on
account of the retention of a part of the aqueous vapor by the soil. In
this case, therefore, the saturated air, after it has passed through the
glass tube around the inside of the box in order to reach the proper
temperature, is conducted into a receptacle of glass which has a number
of connections equal to the number of absorption tubes so that the
saturated air can pass directly into each one of them.
The gases which are to be used for the experiments are prepared in
proper apparatus and are forced through the samples of soil, either by
pressure as in the case of ammonia or carbon dioxid, or by means of
aspirators as in the case of air saturated with aqueous vapor.
The carbon dioxid employed is purified by passing over sodium carbonate
and calcium chlorid.
Public-domain text, read in full here on John Shaqi.
Principles and practice of agricultural analysis. Volume 1 (of 3), Soils — John Shaqi
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