Without displacing the tube from the soil, several samples of gas can be
taken from the same spot. A sufficient number of the bulbs V should be
at hand to hold the required number of samples. Instead of submitting
the sample to eudiometric analysis it is usually sufficient to determine
the quantity of carbon dioxid which it contains, inasmuch as numerous
experiments have shown that in 100 parts of soil gas the oxygen and
carbon dioxid together constitute twenty-one parts. No appreciable trace
of marsh gas, or other combustible gas, has yet been detected in
ordinary arable soils. These gases have only been found in special soils
from marshes, in the neighborhood of gas wells, etc., and not in arable
soils.
[Illustration:
FIGURE 64.
SCHLOESING’S APPARATUS FOR DETERMINATION OF CARBON DIOXID.
]
=286. Apparatus for Estimating the Carbon Dioxid.=—The apparatus used
for determining the carbon dioxid in Schloesing’s work consists of the
apparatus shown in Fig. 64. A represents a glass vessel surrounded by a
jacket of glass, full of water, and sealed on its lower part to the tube
BC of about six millimeters internal diameter. On its upper part it is
sealed to the capillary tube D. The tube BC is graduated from C in
hundredths of the volume of DAC, which volume is about twelve cubic
centimeters. On its lower part it is connected by a rubber tube with a
reservoir F which is capable of being raised or lowered. GHK are
capillary tubes connected together by the rubber tubes L and M, which
are furnished with pinch-cocks. The tube G is connected to a vacuum by
the rubber tube N. The rubber tube should be of very small internal
diameter and from forty to fifty centimeters in length. To the tube H
are sealed, at right angles, the branch D and another branch O. This
last dips into a little mercury which the tube P contains. It serves as
a valve, permitting the exit of the gases but not their entrance. The
tube K carries some lines engraved on its inferior part and is sealed to
the system of the two bulbs Q and R. The bulb Q contains a concentrated
solution of potash. It carries a number of pieces of glass tubing for
the purpose of increasing the surface of the potash solution.
All the parts of the apparatus are fixed upon a rectangular board,
nineteen centimeters broad by twenty centimeters long. This forms one of
the faces of a wooden box to which it is hinged and which serves for the
transportation of the apparatus in a vertical position. The graduation
of the tube BC is recorded behind this tube upon a card fixed upon the
board. By means of these two graduations, the height of the mercury in
the tube BC is most easily read, even when the tube is not perfectly
vertical. Each one of the pinch-cocks L and M, on its upper part is
fixed in a sort of guard which prevents it from being displaced
laterally during the processes of the manipulation, thus avoiding all
danger of breakage.
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