=302. Method of Von Bemmelén.=[195]—According to the view of Von
Bemmelén, the soil contains colloidal humus and colloidal silicate,
which complicate the determination of water. The colloids retain water
in varying quantities, depending upon the following conditions:
(1) Upon their composition and state of molecular equilibrium.
(2) Upon the pressure of the aqueous vapor of the room.
(3) Upon the temperature.
At each degree of temperature, the quantity of absorbed water which a
colloid can retain in a room saturated with aqueous vapor, is different.
The quantity of water which air-dried earth gives off at 100°, has
therefore, no special significance unless all conditions are known.
In addition to the estimation of the quantity of water which soils, in
their natural condition, are capable of taking up and holding, at
ordinary temperatures, the estimation of the quantity of water which
they can take up in different temperatures in rooms saturated with
aqueous vapor should be of interest. It follows, therefore, that there
is no special value in data obtained by drying earth at 100° or 110°.
For the purpose of comparison, he prefers to select that point at which
the soil is dried over sulfuric acid, the point at which the tension of
the water vapor in the earth, at a temperature of plus or minus 15°,
approaches zero. The water which still remains in the earth under these
conditions is characterized as firmly combined water.
Von Bemmelén truly observes that only in soils which contain no
carbonates and no chlorids and sulfids, can the loss on ignition be
regarded as the sum of the humus and water content. By moistening with
ammonium carbonate, the correction for lime or carbon dioxid cannot be
correctly made as has been the custom up to the present time. In the
first place, ignited magnesia, when it has lost its carbon dioxid, does
not take this up completely on moistening with ammonium carbonate; in
the second place, reactions with the chlorids may take place; and in the
third place, the lime which is in the humus will be converted into
calcium carbonate. Chlorids on ignition may be volatilized or oxidized.
The sulfuric acid formed from the sulfids, on ignition, can expel carbon
dioxid; further than this the iron of pyrites takes up oxygen on
ignition. All these influences make the numbers obtained from loss on
ignition extremely variable.
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