The formation of the alkali may be briefly described as follows: By the
decomposition of the native rocks, certain salts soluble in water are
formed. These salts in the present matter are chiefly sodium and
potassium sulfates, chlorids and carbonates. The salts of potash
together with those of lime are more tenaciously held by the soil than
the soluble salts of soda, and the result of this natural affinity of
the soil for soluble potash, lime and magnesian salts is seen in the
formation at the surface of the earth, by the process of evaporation
above described, of a crust of alkaline material which is chiefly
composed of the soluble salts of soda. In countries which have a
sufficient amount of rain-fall, these soluble salts are carried away
either by the surface drainage or by the percolation of water through
the soil, and the sodium chlorid is accumulated in this way in the
waters of the ocean. But where a sufficient amount of rain-fall does not
occur, these soluble salts carried down by each shower only to a certain
depth rise again on the evaporation of the water, reinforced by any
additional soluble material which may be found in the soil itself. The
three most important ingredients of the alkali of the lands referred to
are sodium chlorid, sulfate, and carbonate. When the latter salt,
namely, sodium carbonate, is present in predominant quantity, it gives
rise to what is popularly known as black alkali. This black color is due
to the dark colored solution which sodium carbonate makes with the
organic matters or humus of the soil. The black alkali is far more
injurious to growing vegetation than the white alkali composed chiefly
of sodium sulfate and chlorid.
This black alkali has been very successfully treated by Hilgard[33] by
the application of gypsum which reacting with the sodium carbonate
produces calcium carbonate and sodium sulfate, thus converting the black
into the white alkali and adding an ingredient in the shape of lime
carbonate to stiff soils which tends to make them more pulverulent and
easy of tillage.
This method of treatment, however, as can be easily seen, is only
palliative, the whole amount of the alkaline substances being still left
in the soil, only in a less injurious form.
The only perfect remedy for alkaline soils, as has been pointed out by
Hilgard, is in the introduction of underdrainage in connection with
irrigation. The partial irrigation of alkaline soils, affording enough
moisture to carry the alkali down to and perhaps partially through the
subsoil, can produce only a temporary alleviation of the difficulties
produced by the alkali. Subsequent evaporation may thus increase the
amount of surface incrustation. For this reason in many cases the
practice of irrigation without underdrainage may completely ruin an
otherwise fertile soil by slowly increasing the amount of alkali in the
soil by the total amount of the alkaline material added in the waters of
irrigation.
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