=109. Method of Calculating Results.=—Let t represent the mean
temperature of the beginning period of the experiment, and v equal the
loss in heat per interval. Let t′ and v′ represent the same values for
the end period. Let θ₁, θ₂, θ₃, etc., represent the temperature at the
end of the first, second and third intervals of the middle period and θ₀
the temperature at the beginning of the middle period and θₙ the end
temperature of of the middle period. Let τ₁, τ₂, τ₃, ... τₙ, represent
the mean temperature of the single intervals; then τ₁ = (Θ₀ + Θ₁)/(2);
τ₂ = (Θ₁ + Θ₂)/(2), and τₙ = (Θ_{n–1} + Θₙ)/(2). The constant C
represents the correction which must be applied in order to determine
the true increase of temperature in the calorimetric system. The
expression θₙ − θ₀ + C represents the true temperature increase of the
calorimetric system which we may represent by Δθ and θₙ + C represents
the true maximum, that is, the end temperature, which by exclusion of
external influences is reached. The correction C, as already indicated,
is to be added to θₙ − θ₀ when it is positive and is to be subtracted
therefrom when it is negative. The numerical value of C is usually very
small, and, in the experiments indicated, varied between zero and one
division of the thermometer employed, that is it seldom exceeded one
degree.
=110. Illustration.=—The method of determining value of specific heat is
best illustrated by an example:
In one determination the water value of the calorimetric system,
including stirrer and thermometer was 2.50 grams, the weight of water
added was 97.50 grams and the total water value of the system 100 grams.
The substance was dried at 100° and weighed in five envelopes:
Total weight 31.423 grams.
The envelopes alone weighed 10.654 „
Weight of the soil taken 20.769 „
The envelopes holding the soil were made of brass with zinc ends, the
specific heat of which is 0.0939 and the water value of the whole of the
envelopes was 1.0004 grams. Since, however, the ends were soldered on
with zinc the true water value was somewhat smaller being equal to
0.8692 gram. The data of the observations were as follows:
Corrected height of barometer 699.6 millimeters.
Intervals between the observations 20 seconds.
No. of Temperature on the
Observations. arbitrary scale of the
thermometer.
First Period { 0 162°.6
„ {10 162°.9 = θ₀ (Moment of
immersion.)
Public-domain text, read in full here on John Shaqi.
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