=150. Ammoniacal Nitrogen.=—In ammonia compounds, nitrogen is used
chiefly for fertilizing purposes as sulfate. The ideal nitrogenous
fertilizer would be a combination of the ammoniacal and nitric nitrogen
found in ammonium nitrate. The high cost of this substance excludes its
use except for experimental purposes.
=151. Nitrogen in Guanos.=—The nitrogen in guanos may be found partly
as organic, partly as ammoniacal, and partly as nitric nitrogen. The
high manurial value of guanos and bat deposits in caves, is due not
only to their phosphoric acid, but also to the fact that part of the
nitrogen is immediately available, while a part becomes assimilable
by nitrification during the growing season. The content of nitrogen
in guanos is extremely variable, and depends largely on the climatic
conditions to which the deposit has been subjected. The state in which
it exists is also a variable one, but with a constant tendency to
assume finally the nitric condition.
The well-known habits of birds in congregating in rookeries during
the nights, and at certain seasons of the year, tend to bring into a
common receptacle the nitrogenous matters which they have gathered
and which are deposited in their excrement and in the decay of their
bodies. The feathers of birds are particularly rich in nitrogen, and
the nitrogenous content of the flesh of fowls is also high. The decay
therefore, of remains of birds, especially if it take place largely
excluded from the leaching of water, tends to accumulate vast deposits
of nitrogenous matter. If the conditions in such deposits be favorable
to the processes of nitrification, the whole of the nitrogen, or at
least the larger part of it, which has been collected in this débris,
becomes finally converted into nitric acid, and is found combined
with appropriate bases as deposits of nitrates. The nitrates of the
guano deposits, and of the deposits in caves, arise in this way. If
these deposits be subject to moderate leaching, the nitrate may become
infiltered into the surrounding soil, making it very rich in this form
of nitrogen. The beds and surrounding soils of caves are often found
highly impregnated with nitrates.
While for our purpose, deposits of nitrates only are to be considered
which are of sufficient value to bear transportation, yet much interest
attaches to the formation of nitrates in the soil even when they are
not of commercial importance.
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