At the present time the collection and export of saltpeter from Chile
is a business of great importance. The largest export which has ever
taken place in one year was in 1890, when the amount exported was
927,290,430 kilograms; of this quantity 642,506,985 kilograms were
sent to England and 86,124,870 kilograms to the United States. Since
that time the imports of this salt into the United States have largely
increased.
According to Pissis[130] these deposits are of very ancient origin.
This geologist is of the opinion that the nitrate deposits are the
result of the decomposition of feldspathic rocks, the bases thus
produced gradually becoming united with the nitric acid provided from
the air.
According to the theory of Nöllner[131] the deposits are of more modern
origin, and due to the decomposition of marine vegetation. Continuous
solution of soils beneath the sea gives rise to the formation of great
lakes of saturated water, in which occurs the development of much
marine vegetation. On the evaporation of this water, due to geologic
isolation, the decomposition of nitrogenous organic matter causes
generation of nitric acid, which, coming in contact with the calcareous
rocks, attacks them, forming calcium nitrate, which, in presence of
sodium sulfate, gives rise to a double decomposition into sodium
nitrate and calcium sulfate.
The fact that iodin is found in greater or less quantity in Chile
saltpeter is one of the chief supports of this hypothesis of marine
origin, inasmuch as iodin is always found in sea plants, and not
in terrestrial plants. Further than this, it must be taken into
consideration that these deposits of sodium nitrate contain neither
shells nor fossils, nor do they contain any calcium phosphate. The
theory, therefore, that they are due to animal origin is scarcely
tenable.
Lately extensive nitrate deposits have been discovered in the U.
S. of Columbia.[132] These deposits have been found extending over
thirty square miles and vary in thickness from one to ten feet. The
visible supply is estimated at 7,372,800,000 tons, containing from
1.0 to 13.5 percent of nitrate. The deposits consist of a mixture of
sodium nitrate, sodium chlorid, calcium sulfate, aluminum sulfate, and
insoluble silica. It is thought that the amount of these deposits will
almost equal those in Chile and Peru.
METHODS OF ANALYSIS.
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