_Magnesia._—This is precipitated by ammonium sodium phosphate,
filtered, ignited, and weighed as pyrophosphate. The magnesium is then
calculated as chlorid. Magnesia is rarely found in excess of one-fourth
per cent. When this amount is not exceeded the estimation of it may be
neglected without any great error. As has already been said the chlorin
is all calculated as sodium chlorid. If a part of it be combined with
one-fourth per cent of magnesia it would represent 0.59 per cent of
magnesium chlorid instead of 0.73 per cent sodium chlorid. In omitting
the estimation of the magnesia therefore the importer is only damaged
to the extent of 0.14 per cent of sodium nitrate.
_Sodium Iodate._—This body, present only in small quantities, may also
be neglected. In case the content of this body should reach one-fourth
per cent the estimation of chlorin by titration using potassium
chromate as indicator is impracticable. Such an instance, however, is
rarely known.
_Approximate Results._—When the determinations outlined above have been
carefully made it is claimed that the result obtained by subtraction
from 100 will not vary more than from two-tenths to three-tenths per
cent from the true content of sodium nitrate. The method, however,
cannot be considered strictly scientific and is much more tedious
and chronophagous than the direct determination. In the direct
determination, however, the analyst must assure himself that potassium
is present in only appreciable quantities otherwise the per cent of
sodium nitrate will be too low.
The presence of potassium nitrate is a detriment in this respect
only; _viz._, that it contains a less percentage of nitrogen than
the corresponding sodium salt. As a fertilizer, the value of Chile
saltpeter may be increased by its content of potassium.
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