Kainit occurs as a crystalline, partly colorless, partly yellow-red
mass. When ground, in which state it is sent into commerce, it forms a
fine, gray-colored mass containing many small yellow and red fragments.
It is not hygroscopic and if it become moist it is due to the excess of
common salt which it contains.
According to Maercker kainit was formerly regarded as a potassium
magnesium sulfate. But this conception does not even apply to the pure
salt much less to that which comes from the mines. If, therefore, the
agronomist desire a fertilizer free from chlorin he would be deceived
in choosing kainit which may sometimes contain nearly fifty per cent of
its weight of chlorids.
Where a fertilizer free of chlorin is desired, as for instance, in the
culture of tobacco, kainit cannot be considered. In many other cases,
however, the chlorin content of this body instead of being a detriment
may prove positively advantageous, the chlorids on account of their
easy diffusibility through the soil serving to distribute the other
ingredients.
By reason of the presence of common salt and magnesium chlorid the
ground kainit delivered to commerce tends to harden into compact
masses. To prevent this in Germany it is recommended to mix it with
about two and a half per cent of fine-ground dry peat.
Such a mixture is recommended in all cases where the freshly ground
kainit is not to be immediately applied to the soil.
=238. Carnallit.=—This mineral is a mixture of even molecules of
potassium and magnesium chlorids crystallized with six molecules of
water. It is represented by the symbols KCl·MgCl₂·6H₂O. As it comes
from the mines it contains small quantities of potassium and magnesium
sulfates and small quantities of other accidental impurities. Existing
as it does in immense quantities it has been extensively used for the
manufacture of the commercial potassium chlorid (muriate of potash).
For many purposes in agriculture, for instance, fertilizing tobacco
fields, it is not suited, and it is less widely used as a fertilizer
in general than its alteration product kainit. Its direct use as a
fertilizer however is rapidly increasing since later experience has
shown that chlorin compounds are capable of a far wider application
in agriculture without danger of injury than was formerly supposed.
As it comes from the mines, the Stassfurt carnallit has the following
composition:[199]
Potassium chlorid 15.5 per cent.
Magnesium “ 21.5 “ “
Magnesium sulfate 12.1 “ “
Sodium chlorid 22.4 “ “
Calcium sulfate 1.9 “ “
Water 26.1 “ “
Undetermined 0.5 “ “
Pure carnallit would have the following composition:
Chlorin 38.3 per cent.
Potassium 14.0 “ “
Magnesium 8.7 “ “
Water 39.0 “ “
Equivalent to
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