The residue is digested with hot water, filtered through a small
filter, and washed with successive small portions of water until the
filtrate amounts to thirty cubic centimeters or more. To this filtrate,
add two drops of hydrochloric acid, in a porcelain dish, and from five
to ten cubic centimeters of a solution of ten grams of platinic chlorid
in 100 cubic centimeters of water. The mixture is evaporated on a
water-bath to a thick sirup, as above, treated with alcohol of eighty
per cent strength, washed by decantation, collected in a gooch or other
form of filter, washed with strong alcohol, afterwards with five cubic
centimeters of ether, dried for thirty minutes at 100°, and weighed.
It is desirable, if there be an appearance of foreign matter in the
double salt, that it should be washed, according to the previous
method, with ten cubic centimeters of the half-concentrated solution of
ammonium chlorid, which has been saturated by shaking with potassium
platinochlorid.
=253. Method of Solution for Organic Compounds.=—In case the potash is
contained in organic compounds, like tobacco stems, cottonseed hulls,
etc., weigh ten grams, saturate with strong sulfuric acid, and ignite
in a muffle to destroy organic matter. Add a little strong hydrochloric
acid to moisten the mass and warm slightly so as to loosen it in the
dish. Proceed then as in the lindo-gladding or alternate method.
=254. Factors.=—The use of the factors 0.3056 for converting potassium
platinochlorid to potassium chlorid and 0.19308 for converting it to
potassium oxid is advised. The latter number is almost identical with
that used by the Halle and Stassfurt chemists _viz._, 0.1927 and 0.1928
respectively.
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