_p_ = grams in 100 [_a_]_{D}20° calculated for
grams of solution. anhydrous dextrose.
7.6819 52°.89
9.2994 52°.94
9.3712 52°.94
10.0614 52°.96
10.6279 52°.98
12.9508 53°.05
18.6211 53°.25
31.6139 53°.83
40.7432 54°.34
43.9883 54°.54
53.0231 55°.17
82.6111 57°.80
=107. Gyrodynats of Other Sugars.=—Of the other sugars it will be
sufficient to mention only levulose, maltose, lactose, and raffinose.
For complete tables of gyrodynatic powers the standard books on
carbohydrates may be consulted.[69]
The gyrodynat of levulose is not definitely established. At 14° the
number is nearly expressed by [_a_]_{D}14° = -93°.7.
Invert sugar, which should consist of exactly equal molecules of
dextrose and levulose, has a gyrodynat expressed by the formula
[_a_]_{D}0° = -27°.9, with a concentration equivalent to 17.21 grams of
sugar in 100 cubic centimeters. The gyrodynat decreases with increase
of temperature, according to the formula [_a_]_{D}_t_° = -(27°.9
- 0.32_t_°). According to this formula the solution is neutral to
polarized light at 87°.2, and this corresponds closely to the data of
experiment.
Maltose, in a ten per cent solution at 20°, shows a gyrodynat of
[_a_]_{D}20° = 138°.3.
The general formula for other degrees of concentration is [_a_]_{D} =
140°.375 - 0.01837_p_ - 0.095_t_, in which _p_ represents the number
of grams in 100 grams of the solution and _t_ the temperature of
observation.
In the case of lactose [_a_]_{D} = 52°.53, and this number does not
appear to be greatly influenced by the degree of concentration; but is
somewhat diminished by a rising temperature.
The gyrodynat of raffinose in a ten per cent solution is [_a_]_{D} =
104°.5.
CHEMICAL METHODS OF ESTIMATING SUGARS.
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