=249. Calculation of Results.=—If we represent by a the weight of
metallic copper reduced by the invert sugar present in a solution
containing sucrose, and by _b_ that obtained after the inversion of
the sucrose, the quantity of copper corresponding to the sucrose is _b
- a_ = _c_. After the destruction of the levulose, the copper reduced
by the residual dextrose may be represented by _d_. The weight of
copper equivalent to the levulose is, therefore, _b - d_ = _e_. From
the tables already given, the corresponding quantities of the sugars
equivalent to _c, d_, and _e_ are directly taken. Example:
{ 163.8 milligrams invert sugar.
_a_ = 300 milligrams = { 156.5 ” dextrose.
{ 185.63 ” levulose.
_b_ = 500 ”
_d_ = 275 ” = 142.8 ” dextrose.
_c_ = 200 ” = 106.3 ” invert sugar.
_e_ = 225 ” = 133.89 ” levulose.
The 106.3 milligrams of invert sugar equivalent to _c_, correspond to
101 milligrams of sucrose. The quantity of dextrose equivalent to 275
milligrams of copper is 142.8. Of this amount 53.15 milligrams are
due to the inverted sucrose, leaving 89.65 milligrams arising from
the invert sugar and dextrose originally present. This quantity is
equivalent to 175 milligrams of copper.
Of the 300 milligrams of copper obtained in the first instance, 125
are due to levulose in the original sample, corresponding to 69.73
milligrams which number, multiplied by two, gives the invert sugar
present.
The sample examined, therefore, had the following composition:
Sucrose 101.00 milligrams.
Invert sugar 139.46 ”
Dextrose 19.92 ”
------
Sum 260.38 ”
On the other hand, if the invert sugar be calculated from the quantity
corresponding to the 225 milligrams of copper corresponding to _e_, the
data will be very different from those given above. In this instance of
the levulose found corresponding to 225 milligrams of copper, _viz._,
133.89, 53.15 milligrams are due to the inverted sucrose. Then the
quantity due to the invert sugar at first present is 133.89 - 53.15 =
80.74 milligrams. Since half the weight of invert sugar is levulose,
the total weight of the invert sugar at first present is 161.48,
leaving only 8.91 milligrams due to added dextrose. The difficulties in
these calculations doubtless arise from the imperfect destruction of
the levulose, and from variations in the reducing action of sugars on
copper salts in the presence of such large quantities of sodium chlorid.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account