Lead oxid is regenerated from the basic lead carbonate obtained by
heating in retorts to a little above 260°, and the carbon dioxid
evolved can also be used again in the technical process.
=253. Commercial Glucose and Grape Sugar.=—The commercial products
obtained by the hydrolysis of starch are known in the trade as glucose
or grape sugar. The former term is applied to the thick sirup obtained
by concentrating the products of a partial hydrolysis, while the latter
is applied to the solid semi-crystalline mass, secured by continuing
the hydrolyzing action until the intermediate products are almost
completely changed to dextrose. In this country the starch employed
is obtained almost exclusively from maize, and the hydrolyzing agent
used is sulfuric acid.[208] The products of conversion in glucose are
chiefly dextrins and dextrose with some maltose, and in grape sugar
almost entirely dextrose. When diastase is substituted for an acid, as
the hydrolytic agent, maltose is the chief product, the ferment having
no power of producing dextrose. In the glucose of Japan, known as midzu
ame dextrin and maltose are the chief constituents.[209]
Commercial glucose is used chiefly by confectioners for manufacturing
table sirups and for adulterating honey and molasses.
Commercial grape sugar is chiefly employed by brewers as a substitute
for barley and other grains.
In Europe, the starch which is converted into glucose, is derived
principally from potatoes. The method employed in conversion, whether
an acid or diastatic action, is revealed not only by the nature of
the product, but also by the composition of its ash. In the case of
diastatic conversion the ash of the sample will contain only a trace of
sulfates, no chlorin, and be strongly alkaline, while the product of
conversion with sulfuric acid will give an ash rich in sulfates with a
little lime and be less strongly alkaline.
The process of manufacture in this country consists in treating the
starch, beaten to a cream with water, with sulfuric acid, usually under
pressure, until the product shows no blue color with iodin. The excess
of acid is removed with marble dust, the sirup separated by filtration,
whitened by bleaching with sulfurous acid or by passing it through
bone-black and evaporated to the proper consistence in a vacuum. The
solid sugar, consisting mostly of dextrose, is made in the same manner,
save that the heating with the acid is continued until the dextrin and
maltose are changed into maltose. The product is either obtained in
its ordinary hydrated form or by a special method of crystallization
secured as bright anhydrous crystals. Solutions of dextrose, when first
made, show birotation, but attain their normal gyrodynatic state on
standing for twenty-four hours in the cold, or immediately on boiling.
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