=278. Composition.=—Fats and oils are composed chiefly of salts
produced by the combination of the complex base glycerol with the fat
acids. Certain glycerids, as the lecithins, contain also phosphorus
in organic combinations, nitrogen, and possibly other inorganic
constituents in organic forms. By the action of alkalies the glycerids
are easily decomposed, the acid combining with the inorganic base and
the glycerol becoming free. The salts thus produced form the soaps
of commerce and the freed base, when collected and purified, is the
glycerol of the trade.
When waxes are decomposed by alkalies, fatty acids and alcohols of the
ethane series are produced.
The natural glycerids formed from glycerol, which is a trihydric
(triatomic) alcohol, are found in the neutral state composed of three
molecules of the acid, united with one of the base. If R represent the
radicle of the fat acid the general formula for the chemical process by
which the salt is produced is:
Glycerol. Acid. Salt. Water.
O.H O.R
C₃H₅O.H + 3R.OH = C₃H₅O.R + 3H₂O.
O.H O.R
The resulting salts are called triglycerids or neutral glycyl
ethers.[230] In natural animal and vegetable products, only the neutral
salts are found, the mono- and diglycerids resulting from artificial
synthesis. For this reason the prefix tri is not necessarily used in
designating the natural glycerids, stearin, for instance, meaning the
same as tristearin.
=279. Principal Glycerids.=—The most important glycerids which the
analyst will find are the following:
Olein, C₃H₅O(O.C₁₈H₃₃O)₃.
Stearin, C₃H₅O(O.C₁₈H₃₅)₃.
Palmitin, C₃H₅O(O.C₁₆H₃₁O)₃.
Linolein, C₃H₅O(O.C₁₈H₃₁O)₃.
Butyrin, C₃H₅O(O.C₄H₇O)₃.
Olein is the chief constituent of most oils; palmitin is found in palm
oil and many other natural glycerids; stearin is a leading constituent
of the fats of beeves and sheep, and butyrin is a characteristic
constituent of butter, which owes its flavor largely to this glycerid
and its nearly related concomitants.
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