There are many instances, however, where other solvents should be used.
The use of aqueous alcohol is sometimes preceded by that of alcohol of
greater strength or practically free of water. For the extraction of
soluble carbohydrates (sugars) cold or tepid water is employed, the
temperature of which is not allowed to rise high enough to act upon
starch granules. For the solution of the starch itself an acid solvent
is used at a boiling temperature, whereby the starch molecules undergo
hydrolysis and form dextrin or soluble sugars (maltose, dextrose). By
this process also the carbohydrates, whose molecules contain five, or
some multiple thereof, atoms of carbon form soluble sugars of which
xylose and arabinose are types. The solvent action of acids followed
by treatment with dilute alkalies at a boiling temperature, completes
practically the solution of all the carbohydrate bodies, save cellulose
and nearly related compounds. The starch carbohydrates are further
dissolved by the action of certain ferments such as diastase.
Dilute solutions of mineral salts exert a specific solvent action on
certain nitrogenous compounds and serve to help separate the albuminoid
bodies into definite groups.
Under the proper headings the uses of these principal solvents will be
described, but a complete discussion of their action, especially on
samples of a vegetable origin, should be looked for in works on plant
analysis.[20]
The application of acids and alkalies for the extraction of
carbohydrates, insoluble in water and alcohol, will be described,
in the paragraphs devoted to the analysis of fodders and cereals.
The extraction of these matters, made soluble by ferments, will be
discussed in the pages devoted to starch and artificial digestion.
It is thus seen that the general preliminary treatment of a sample
preparatory to specific methods of examination is confined to drying,
extraction with ether and alcohol, and incineration.
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