In very warm weather the apparatus may be arranged as shown in figure
24. The bath for holding the extraction tubes is made in two parts,
K and Kʹ. The bath K has a false bottom shown in the dotted line O,
perforated to receive the ends of the extraction tubes and which holds
them in place and prevents them from touching the true bottom, where
they might be unequally heated by the lamp. The upper bath Kʹ has a
perforated bottom, partly closed with rubber-cloth diaphragms Gʹ Nʹ Hʹ.
The extraction tubes passing through this bath, water-tight, permit
broken ice or ice-water to be held about their tops, and thus secure
a complete condensation of the vapors of the solvent which in warm
weather might escape the metal condenser. In practice care must be
taken to avoid enveloping too much of the upper part of the extraction
tube with the ice-water, otherwise the vapors of the solvent will be
chiefly condensed on the sides of the extraction tube and will not be
returned through the sample. It is not often that the upper bath is
needed, and then only with ether, never with alcohol. This apparatus
has proved especially useful with alcohol, using, as suggested,
glycerol in the bath. The details of its further construction and
arrangement are shown in the figure. The extraction tubes are most
conveniently arranged in a battery of four, one current of cold water
passing in at A and out at B, serving for all. The bath is supported
on legs long enough to allow the lamp plenty of room. The details of
the condenser M are shown in Bʹ, Aʹ, T, Fʹ, and Lʹ. Instead of a gooch
Lʹ for holding the sample a glass tube R, with a perforated platinum
disk Q, may be used. The water line in the bath is shown by W. This
apparatus may be made very cheaply and without greatly impairing its
efficiency by using a plain concentric condenser and leaving off the
upper bath Kʹ.
=42. Solvents Employed.=—It has already been intimated that the chief
solvents employed in the extraction of agricultural samples are ether
or petroleum and aqueous alcohol. The ether used should be free of
alcohol and water, the petroleum should be subjected to fractional
distillation to free it of the parts of very high and very low boiling
points, and the alcohol as a rule should contain about twenty per cent
of water.
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