The simplest method of determining the density of a solution is to
get the weight of a definite volume thereof. This is conveniently
accomplished by the use of a pyknometer. A pyknometer is any vessel
capable of holding a definite volume of a liquid in a form suited
to weighing. It may be a simple flask with a narrow neck distinctly
marked, or a flask with a ground perforated stopper, which, when
inserted, secures always the same volume of liquid contents. A very
common form of pyknometer is one in which the central stopper carries a
thermometer and the constancy of volume is secured by a side tubulure
of very small or even capillary dimensions, which is closed by a ground
glass cap.
The apparatus may not even be of flask form, but assume a quite
different shape as in Sprengel’s tube. Pyknometers are often made to
hold an even number of cubic centimeters, but the only advantage of
this is in the ease of calculation which it secures. As a rule, it
will be found necessary to calibrate even these, and then the apparent
advantage will be easily lost. A flask which is graduated to hold fifty
cubic centimeters, may, in a few years, change its volume at least
slightly, due to molecular changes in the glass. Some of the different
forms of pyknometers are shown in the accompanying figures.
In use the pyknometer should be filled with pure water of the desired
temperature and weighed. From the total weight the tare of the flask
and stopper, weighed clean and dry, is to be deducted. The remainder
is the weight of the volume of water of the temperature noted, which
the pyknometer holds. The weight of the solution under examination is
taken in the same way and at the same temperature, and thus a direct
comparison between the two liquids is secured.
_Example._—Let the weight of the pyknometer be 15.2985 grams.
and its weight with pure water at 15°.5 be 26.9327 ”
Then the weight of water is 11.6342 ”
The weight filled with the sugar solution is 28.3263 ”
Then the weight of the sugar solution is 13.0278 ”
The specific gravity of the sugar solution is therefore, 13.0278 ÷
11.6342 = 1.1198.
For strictly accurate results the weight must be corrected for the
volume of air displaced, or in other words, be reduced to weights in
vacuo. This however is unnecessary for the ordinary operations of
agricultural analysis.
If the volume of the pyknometer be desired, it can be calculated from
the weight of pure water which it holds, one cubic centimeter of pure
water weighing one gram at 4°.
The weights of one cubic centimeter of water at each degree of
temperature from 1° to 40°, are given in the following table:
TABLE SHOWING WEIGHTS OF ONE CUBIC CENTIMETER OF
PURE WATER AT TEMPERATURES VARYING FROM 1° TO 40°.
Weight, Weight,
Temperature. Gram. Temperature. Gram.
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