=83. Preparing Sugar Solutions for Polarization.=—If sugar samples
were always pure the percentage of sugar in a given solution could be
directly determined by immediate polarization. Such cases, however,
are rarely met in practice. In the majority of cases the sample is
not only to be brought into solution but is also to be decolorized
and rendered limpid by some one of the methods to be described. A
perfectly limpid liquid is of the highest importance to secure correct
observations. With a cloudy solution the field of vision is obscured,
the dividing line of the two halves, or the double line in the triple
field, becomes blurred or invisible and the intensity of illumination
is diminished. A colored liquid which is bright is far more easy to
polarize than a colorless liquid which is turbid. In fact, it is only
rarely in sugar work that samples will be found which require any
special decolorizing treatment other than that which is received in
applying the reagents which serve to make the solutions limpid. In the
following paragraphs the approved methods of clarifying sugar solutions
preparatory to observation in the polariscope will be described.
=84. Alumina Cream.=—The hydrate of alumina, commonly known as alumina
cream, is always to be preferred as a clarifying agent in all cases
where it can be successfully applied.[46] It is a substance that acts
wholly in a mechanical way and therefore leaves the sugars in solution
unchanged, carrying out only suspended matters. In the preparation
of this reagent a solution of alum is treated with ammonia in slight
excess, the aluminum hydroxid produced washed on a filter or by
decantation until neutral in reaction. The hydroxid is suspended
in pure water in proportions to produce a creamy liquid. Although
apparently very bulky, the actual space occupied by the amount of dry
hydroxid added in a few cubic centimeters is so small as to produce no
disturbing effect of importance on the volume of the sugar solution.
The cream thus prepared is shaken just before using and from one to
five cubic centimeters of it, according to the degree of turbidity of
the saccharine solution, are added before the volume in the flask is
completed to the mark. After filling the flask to the mark the ball of
the thumb is placed over the mouth and the contents well shaken and
allowed to stand for a few moments before filtering.
The alumina cream is well suited to use with solutions of commercial
sugars of not too low a grade and of most honeys and high grade
sirups. It is usually not powerful enough to clarify beet and cane
juices, molasses and massecuites.
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