Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
aniline are, para-phenylene-diamine, dimethyl-para-phenylene-diamine,
para-amido-diphenylamine, para-amido-phenol, etc.”
This method may be used alone as the other Aniline Blacks, or the dyed
skins may be after-dyed in a bath containing a logwood dye, or it may be
used in conjunction with mineral dyes, or with the Oxidation Colors (see
next chapter). A typical formula for the black by Green’s process is the
following:
Para-amido-phenol 0.5 kg.
Aniline oil 10 liters
Hydrochloric acid 22° Bé. 10 liters
Acetic acid 40% 5 liters
Cold water 25 liters
This is solution A. Solution B is prepared by dissolving
Copper sulphate 2 kg.
Salammoniac 10 kg.
Cold water 50 liters
A and B are mixed, and the mixture applied to the hair of the furs several
times, drying each time at 35°–40° C. After three coats of dye have
been applied, a pretty and fairly intense black shade is obtained, which
is developed further by treating with a solution of 25 grams of sodium
bichromate per liter of water. The skins are then allowed to dry in air,
and then if desired, an after-dyeing is made with some other dye.
On account of its extreme fastness, Aniline Black, produced by any of
the methods outlined above, has attained a justifiable popularity for
the dyeing of furs, in spite of the necessity of using the more or less
cumbersome brush method of applying the dye. Very recently there was
issued to a German company a patent in which is described a method whereby
furs can be dyed with Aniline Black by the dip process. An abstract of
the patent (D. R. P. 33402) is as follows: “As is known, aniline salt,
and similar salts, together with oxidizing agents like bichromates,
chlorates, etc., cannot be used for dyeing furs by the dip process,
because the strongly dissociated mineral acid is injurious to the leather.
The dissociation of the acid can be reduced by adding neutral salts, like
common salt, or Glauber’s salt, so that good results can be obtained by
dyeing in a bath of the dye mixture, the leather retaining its softness.”
Thus far there have been no reports of the successful practical
application of this patent, so its value cannot be discussed. It is
extremely doubtful, however, that furs will ever be dyed in the dyebath
with the present type of Aniline Black formulas, no matter what substances
are added to prevent the leather from being affected.
CHAPTER XV
FUR DYEING
OXIDATION COLORS
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