Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
The para-phenylene-diamine can be replaced in this process by other
similar bases, such as dimethyl-para-phenylene-diamine, as well as the
naphthylene-diamines. Since the substances which can be applied by this
process are uninjurious, the method described can be used to dye human
hair on the head or beard, and so seems suited to replace for the dyeing
of hair, the metallic salts and various pyrogallic solutions which are on
the market, and which are harmful to the health.
D. R. P. 51073 Supplement to 47349; Process for Dyeing Hair
This patent was an extension of the original patent to include certain oxy
and amido-oxy compounds, the method being essentially the same otherwise
as in the original patent. An illustration of the process is as follows:
73 grams para-amido phenol hydrochloride are dissolved with 40 grams
caustic soda in a liter of water. The solution dyes hair a golden-yellow,
which on subsequent treatment with a solution of ferric chloride turns to
a red-brown.
In these two patents is to be found the basis of the modern fur dyes
and fur dyeing methods. It is interesting to note that furs were not
mentioned at all in connection with the process, which was intended
mainly for dyeing hair, especially on the human head. It was only several
years later that the value of the method for dyeing furs was realized.
So about 1894, the Aktien Gesellschaft für Anilinfabrikation put upon
the market three fur dyes under the trade name Ursol, Ursol D, giving
dark-brown to black shades; Ursol P, giving red-brown colors; and Ursol
C, giving a yellowish-brown shade. Pyrogallic acid had been previously
used as a hair dye, and also to a slight extent as a fur dye, so it was
used in conjunction with the Ursol dyes for shading purposes. The new fur
dyes were not dyes in the ordinarily accepted sense of the term. They
were really coal-tar intermediates, substances similar in character to
aniline, and their dyeing property depended on the fact that they could
be oxidized either by atmospheric oxygen, or by means of oxidizing agents,
forming colored insoluble products. When the oxidation of the intermediate
was caused to take place on the hair the colored product formed on and
in the hair fibre, and remained fast. The reactions bringing about the
conversion of the intermediate to the colored insoluble compound are quite
analogous to those of the Aniline Black process, though possibly not so
complicated, with the important difference, however, that, while in the
production of Aniline Black acid is essential, in the present instance the
oxidation can be carried on in neutral or even alkaline medium. On account
of the character of the method used in applying the new fur dyes, the
name Oxidation Colors has been given to them. Strictly speaking, Aniline
Black is also an Oxidation dye, but it is usually considered in a class
by itself. The methods used at first in the application of the Ursol dyes
Public-domain text, read in full here on John Shaqi.
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