Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
The lactic acid fermentation processes have an advantage over the pickle,
in that the slow formation of weak organic acids with their gradual action
produce a softer leather, with a gentler ‘feel,’ the presence of the flour
and the grains of the tan, aside from their tanning action, contributing
to the fullness and softness of the leather. There is also less likelihood
of the leather being subsequently affected by the presence of the acid
in it, as lactic and acetic acids are much less injurious than sulphuric
acid to leather. These disadvantages of the pickle can to a large degree,
be overcome without any great difficulty. On the other hand, the matter
of the length of time of the tanning process, shows the acid pickle at
a great advantage, and so, especially for furs other than those obtained
from sheep and goats, the pickle is in most cases used as the principle
method of tanning. In Austria, Russia, and to a certain extent in Germany
also, the “Schrot-beize” is still considerably employed, chiefly for
dressing sheep and lamb skins. The dressing of the various kinds of
Persian lambs, caraculs, astrachans, etc., in the native center of the
industry in Buchara and surrounding districts, is also a “Schrot-beize,”
barley, rice flour or rye flour, and salt water being used to prepare the
skins, the manipulations being essentially the same as those described
above, although carried out in cruder and more primitive fashion.
2. MINERAL TANS
The basis of the tanning of furs by means of solutions of mineral
compounds is the fact that the basic salts of certain metals are capable
of producing leather. It has been found that compounds of aluminum such as
alum or aluminum sulphate, or any other soluble neutral salt of aluminum,
possess tanning powers. Other metals which are capable of forming salts
of the same type are also endowed with the quality of converting skin
to leather under suitable conditions, chromium and iron being the most
important metals in this connection. Chemically these metals all belong
to the same group, and have properties which are very similar in many
respects, the characteristic of most importance for tanning purposes
being the quality of forming soluble basic salts by the addition of
alkalies or alkaline carbonates to solutions of their neutral salts, or
in certain instances simply by the action of water upon these neutral
salts. By neutral salts are meant those in which the metallic content is
combined with the normal proportion of acid; while basic salts are those
in which the acidic portion is present in less than the normal ratio,
being partially replaced by a hydroxide group. When the acid part of
the salt has been entirely replaced in this way, the compound is called
a hydroxide or hydrate of the metal. Between the neutral salt and the
hydroxide several different basic salts are possible, some being soluble,
while others are insoluble. If into a solution containing a basic salt of
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