either aluminum, iron or chromium a skin be entered, a part of the basic salt will be precipitated on it in insoluble form. Inasmuch as neutral salts of these metals when dissolved in water split up to a small degree, into free acid and soluble basic salt, a skin immersed in such a solution will also absorb the basic salt in an insoluble form. Upon these facts in general, depends the action of the mineral tans used in tanning furs. A. _Alum Tan_ The alum tan is one of the oldest methods of producing leather, being employed by the Romans about two thousand years ago, and it is believed, by the Egyptians at a much earlier period. Its extensive use in Europe, however, dates from the time of the conquest of Spain by the Moors, who introduced the process. At the present time, rabbits and moles are tanned by this process, as are also at times other furs such as muskrats, squirrels, sables, martens, etc., when a better tan is desired than that produced by the pickle. Ordinary alum, which is a double sulphate of aluminum and potassium, and aluminum sulphate are the chief compounds used for this tan. In recent years, the aluminum sulphate has to a considerable degree replaced the alum for tanning, inasmuch as it can be cheaply obtained in a sufficiently pure form, and contains about one and one-half times as much active aluminum compound as does alum. While the aluminum salt can be used alone for tanning, it produces a stiff, imperfect leather, so salt is always added. The ratio of the salt to the aluminum sulphate or alum can vary within rather wide limits, the mixtures used in practise ranging from one part of salt to four parts of the aluminum compound, up to equal parts of both, or even in some formulas, a greater proportion of salt than of the other constituent. Ratios which are most common are four of alum to three of salt, or two of alum to one of salt. When aluminum sulphate is dissolved in water, a small part of it splits up into a soluble basic salt and an equivalent amount of free acid. The reaction may be shown as follows: Al₂(SO₄)₃ + 2H₂O = Al₂(SO₄)₂(OH)₂ + H₂SO₄ aluminum water basic aluminum sulphuric sulphate sulphate acid