Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
Formaldehyde has proven to be of great value in the tanning of furs,
usually in conjunction with other processes. Formaldehyde is a gas with
a strong, irritating odor, and its 40% solution, which is the customary
commercial form, also possesses this quality. When skins are treated for
several hours with a very dilute solution of the commercial product, a
leather is obtained which combines the properties of the alum tan and
the chamois tan. Moreover, in the majority of observed cases, where furs
have been tanned with formaldehyde, the skins seem to acquire a certain
immunity to the attacks of vermin and moths. Although the skins do
not in any way retain the odor of the formaldehyde, nevertheless these
destructive agents seem to be repelled.
Numerous processes have been devised which use formaldehyde in connection
with other substances for tanning. Thus in a German patent is described
a method involving the alternate or simultaneous treatment of pelts
with solutions of formaldehyde and alpha or beta naphthol. Both the
formaldehyde and the naphthol exercise tanning actions, but the process
is not used in practise.
In 1911, Stiasny, a well-known leather chemist produced a synthetic
substance by the condensation of formaldehyde with a sulphonated phenol,
forming an artificial tannin. This chemical, called “Neradol D,” exhibits
many of the properties characteristic of true tannins, although in no way
related by structure and composition. By the use of “Neradol D” a soft,
white and flexible leather is obtained, and it is therefore a suitable
tanning material for furs.
5. COMBINATION TANS
In many instances more than one method is employed in tanning the furs,
and in this way what is known as a combination tan is produced. While the
various individual processes described give more or less satisfactory
results by themselves, they generally possess some features, which
for certain purposes may be undesirable, and which can be eliminated
or considerably reduced by using other processes at the same time or
subsequently. Some of the combination methods are, pickle with chrome
tan, alum tan with chrome tan, and formaldehyde tan with pickle, mineral
tan or chamois tan. By means of such combinations various qualities of
tanned furs can be obtained, and if it is desired to produce a pelt having
certain special characteristics, this can be brought about by combining
two or more standard methods.
Some illustrations of combined tannages are the following: Alum-chrome
tan. The skins are tanned by the regular alum process, then the
constituents of the chrome tan are dissolved directly in the same bath,
and the chrome tan is effected as usual. Chrome-formaldehyde tan. To the
regular chrome tan solution is added 1/2 lb. of formaldehyde for every 10
gallons of chrome liquor. The rest of the process is as ordinarily.
6. VEGETABLE TANS
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