Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
The dyeing of furs with mineral colors involves the precipitation on
the fibre in a more or less permanent form of the sulphide, oxide or
other insoluble compound of a metal, and can be brought about in several
ways. By what is known as double decomposition, that is, by the use
of two solutions successively applied, the ingredient of one causing a
precipitate to form when in contact with the constituent of the second,
the color is produced on the hair. Another method is to use solutions of
chemicals which decompose on contact with the hair, forming an insoluble
compound. In the first method the hair is alternately treated with the
two solutions of the requisite chemicals, drying between each brushing,
the process being repeated until the desired shade is obtained. The second
method merely requires the solution of the chemical to be applied to the
hair, which is then dried, the color forming by itself.
One of the most important of the mineral dyes, and which is occasionally
used to this day, is lead sulphide, formed by the double decomposition
method by precipitating a soluble lead salt with ammonium sulphide, or any
other alkaline sulphide. By simply brushing an aqueous solution of lead
acetate, also known as sugar of lead, on a white fur such as white hare or
rabbit, a light, brownish coloration is obtained due to the combination of
the lead with the sulphur of the hair. If the lead solution is carefully
applied several times on this type of fur, until a sufficiently dark
color is produced, it is possible to get a fairly good imitation of the
stone marten. The brown color is very fast, being actually formed within
the hair. In most cases, however, for dyeing lead sulphide shades it is
necessary to use the two solutions. Thus the pale greyish or slightly
brownish-grey shades of the lynx can be reproduced on white rabbit or
hare by this process. A solution containing 60 grams of lead acetate per
liter of water is brushed on to the hair of the fur which has previously
been killed in the usual manner, and the hair is then dried. A solution
of 50 grams of ammonium sulphide per liter of water is next brushed on,
and the fur again dried. Care must be exercised in handling the ammonium
sulphide as it is a very malodorous liquid, the fumes of which are
poisonous when inhaled. The alternate brushings are repeated until the
desired depth of shade is obtained. A very dark brown, approaching a black
can be obtained in this way. This color can be used for the production of
certain attractive effects. By brushing over the tips of the hair, which
has previously been dyed a dark brown by means of the lead sulphide color,
with a dilute solution of hydrochloric acid, or with peroxide of hydrogen,
the hair will become white in the parts so treated, due to the formation
of lead chloride or lead sulphate, respectively. Thus white tipped furs
can be obtained, but the process is applicable only when the furs have
been dyed by the lead sulphide method.
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