Proceedings of the California Academy of Sciences, Volume III, 1863-1867Various
Science
Proceedings of the California Academy of Sciences, Volume III, 1863-1867
Various
California Academy of Sciences -- Periodicals; Science -- Periodicals
In the specimen in my possession, the mineral occurs filling
seams in the guano, varying from ⅛ to ¼ of an inch in width.
The matrix itself is of the variety known as rock guano. It
possesses an oolitic structure and a brownish white color,
interspersed with small spots of pure white.
The mineral is in the form of small but very perfect and
brilliant crystals with a cleavage in the direction of their
greatest length, nearly equal to that of selenite; the laminæ,
being also slightly flexible, as in the case of the latter
species. Hardness, 2.25 (Moh’s scale). Specific gravity,
2.208, (mean of two determinations). Color, yellowish white.
Transparent. Lustre, vitreous splendent, inclining to pearly on
the cleavage faces.
When heated in a closed tube before the blowpipe, it whitens
and gives off water, at an incipient red heat. In the platina
forceps, it fuses with intumescence, at about 2. of Von
Kobbell’s scale, tinging the flame with the peculiar green
characteristic of phosphoric acid. The button formed by fusion,
crystallizes on cooling, showing numerous brilliant facets.
Readily soluble, even in coarse crystals, in dilute nitric and
hydrochloric acids.
A qualitative analysis, revealed the presence of Lime,
Phosphoric acid, and water, with barely discernable traces of
Magnesia and Alumina.
The quantity of mineral at my disposal was very small, scarcely
exceeding one gramme in weight. In each of the following
analyses, the water was determined in 0.2 grammes, the
remaining 0.3 grammes being employed in the determination of
the Lime and Phosphoric acid. The results were as follows:
1. 2.
Lime 32.65 32.73
Phosphoric acid 41.50 41.32
Water 26.33 26.40
------ ------
100.48 100.45
These figures agree exactly with the composition of the neutral
tri-basic phosphate of lime (2 CaO., H O, P O₅), with the
addition of four equivalents of water of crystallization, (2
CaO, H O, P O₅ + 4 aq.) viz.:
2 CaO 56.26 = 32.59
P O₅ 71.36 = 41.34
H O 9.00 } = 26.07
4 Aq 36.00 }
------ ------
172.62 100.00
In the polarizing microscope, the mineral shows a vivid
succession of colors. A sample has been sent to Prof.
J. D. Dana, who has kindly undertaken the study of its
crystallographic characters, and I hope, in a short time, to be
able to communicate the results of his investigations to the
Academy.
It is with very great pleasure, that I dedicate this species
to Prof. Geo. J. Brush, of Yale College, to whose unwearied
zeal and efficient labors, American Mineralogy stands so deeply
indebted.
REGULAR MEETING, SEPT. 19TH, 1864.
President in the Chair.
Public-domain text, read in full here on John Shaqi.
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