Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
Copper and iron are still used to a limited extent in these pyrometers,
but lose continuously in weight by oxidation, the scales of oxide
falling off when quenched, necessitating weighing before each test
to ensure accuracy. Nickel oxidises very little below 1000 C., and
as the thin film of oxide which forms does not readily peel off, the
weight may increase slightly. Quartz would probably be more suitable
than metals, not being altered by heating and quenching, but does not
appear to have been tried for this purpose. Another possible material
is nichrom, which resists oxidation below 1000° C. The weight of the
solid should be at least 1/20 of that of the water, in order to ensure
a tangible rise in temperature, and the thermometer should be capable
of detecting 1/20 of a degree C. The rise in temperature should not be
so great as to cause the water to exceed the atmosphere in temperature
by more than 4° or 5° C., as otherwise radiation losses would have a
marked effect. The limits of accuracy of the method will be shown by
reference to examples.
_Example I._—A piece of nickel, weighing 100 grams, is
placed in a furnace, and after heating dropped into 2000
grams of water at 10° C., contained in a vessel of water
equivalent 50 grams. The temperature rises to 16·25° C.
The specific heat of nickel for the range is 0·137. To
find the temperature of the furnace and the limits of
accuracy, the thermometer being readable to 1/20° C.
Equating heat lost by the nickel to that gained by the
water and vessel:—
100 × 0·137 × (_x_ - 16·25) = 2050 × (16·25 - 10·0)
from which _x_ = 952° C.
If the error in each thermometer reading amounted to
1/40° the maximum difference in the above calculation is
obtained by introducing the altered values as under:—
100 × 0·137 × (_x_ - 16·225) = 2050 × (16·225 - 10·025)
when _x_ = 944° C.
The maximum error due to a possible incorrect reading of
1/40° is therefore less than 1 per cent.
_Example II._—The loss of heat by radiation in transferring
100 grams of nickel at 927° C., possessing a surface of
30 square centimetres, and with radiating power 0·7 of a
black body, may be shown by the fourth-power law to be 50
calories per second (see page 139). If two seconds were
occupied in the transfer, the error from this cause would
be 1 in 130; and adding this to the thermometric error,
the total is less than 2 per cent.
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