Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
=Special Uses of Calorimetric Pyrometers.=—The great drawback
to the calorimetric method is that each observation necessitates a
separate experiment, involving time and labour. The accuracy, moreover,
is not comparable with that obtainable by the use of a thermo-electric
or resistance pyrometer; and practically the only recommendation
is the low initial cost of the outfit. When an occasional reading
of temperature, true to 3 per cent., suffices, the calorimetric
pyrometer may be used; and in special laboratory determinations the
method will frequently be found of value. Considering the low cost of
thermo-electric pyrometers at the present time, it is probable that
the calorimetric method will be entirely superseded in industrial
practice, as the former method gives a continuous, automatic reading,
and is capable of furnishing records. Many firms have already replaced
their “water” pyrometers by the more accurate and useful appliances now
available.
CHAPTER VIII
FUSION PYROMETERS
=General Principles.=—If a number of solids, possessing
progressive melting points, be placed in a furnace and afterwards
withdrawn, some may be observed to have undergone fusion whilst others
would be unaffected. The temperature of the furnace would then be known
to be higher than that of the melting point of the last solid melted,
and lower than that of the first which remained intact. Taking, for
example, a series of salts, the following might be used:-
══════════════════════════════════════╤═════════════════════
│ Melting Point.
Salt. ├──────────┬──────────
│Deg. Cent.│Deg. Fahr.
──────────────────────────────────────┼──────────┼──────────
1 molecule common salt + │ 650 │ 1202
1 molecule potassium chloride │ │
Common salt │ 800 │ 1472
Anhydrous sodium carbonate │ 850 │ 1562
” ” sulphate │ 900 │ 1652
Sodium plumbate │ 1000 │ 1832
Anhydrous potassium sulphate │ 1070 │ 1958
” magnesium sulphate │ 1150 │ 2102
══════════════════════════════════════╧══════════╧══════════
If, on inspection, it were found that the sodium sulphate had melted,
whilst the sodium plumbate had survived, the temperature of the furnace
would be known to lie between 900° C. and 1000° C. If a number of salts
or other solids could be found with melting points ranging between 900°
and 1000°, it would be possible to obtain a reading within narrower
limits. The accuracy of the method in all cases is decided by the
interval between the melting points of successive test materials.
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