Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
=Advantages of the Thermo-electric Method of Measuring
Temperatures.=—Compared with other methods, the thermo-electric
possesses the following points of superiority:—(1) Simplicity, no
special experiment being necessary to obtain a reading; (2) cheapness
of outfit; (3) adaptability to a variety of purposes; (4) ease of
repair in case of damage; (5) robustness, not being liable to get
out of order under workshop conditions; and (6) suitability to the
purpose of a centrally controlled installation. The drawbacks are:—(1)
Liability to error owing to fluctuations in the cold junction (which
may be avoided with care); and (2) lack of sensitiveness at very high
temperatures compared with the resistance method—a point seldom of
great practical importance, as the limit of accuracy is usually within
the amount by which an ordinary furnace fluctuates in temperature under
working conditions.
CHAPTER IV
RESISTANCE PYROMETERS
=General Principles.=—When a pure metal is heated, its resistance
to electricity increases progressively with the temperature. Certain
alloys, on the other hand, show a practically constant resistance at
all temperatures, examples of such alloys being constantan, manganin,
and platinoid. All the elementary metals, however, exhibit a tangible
rise in resistance when the temperature is augmented; and Sir W.
Siemens, in 1871, proposed to apply this principle to the measurement
of high temperatures by determining the resistance, and deducing the
corresponding temperature from a table prepared under known conditions.
The choice of a metal is in this case more greatly restricted than in
the selection of materials for a thermal junction. A certain amount
of external corrosion does not alter the E.M.F. of a junction; but an
alteration in size produces a marked difference in the resistance of
a wire, which varies directly as the length and inversely as the area
of cross-section. To the necessity for the absence of any internal
physical change affecting the resistance is therefore added the further
condition of permanence of external dimensions. For temperatures
above a red heat the only feasible metals to use are platinum or the
more expensive metals of the platinum series—and hence platinum is
universally employed for this purpose. The original Siemens pyrometer
consisted of 1 metre of platinum wire, 1 millimetre in diameter,
wrapped round a porcelain rod, and protected from furnace gases by an
iron sheath An elaborate method of measuring the resistance, involving
the electrolysis of acidulated water, was adopted for workshop use,
but was too involved to become popular. Later, Siemens employed the
differential galvanometer method, and finally the Wheatstone bridge,
to measure the resistance. Both methods are still in use in connection
with resistance pyrometers, and the principle of each will now be
explained.
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