Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
=Measurement of Low Temperatures.=—Junctions of iron and
constantan, Hoskin’s alloys, copper and German silver, or copper and
constantan, are suited to these measurements. In a laboratory the
cold junction may be kept in ice in a Dewar vessel, the mechanically
protected form known as the “Thermos” flask being very useful for this
purpose. With a good mirror galvanometer precise readings may be
secured, 1/10 of a degree C. being easily detected. Calibration between
-40° and +40°C. may be effected by comparison with a standard mercury
thermometer, a water-bath being used above 0°, and alcohol surrounded
by a freezing mixture of ice and calcium chloride crystals below
zero. For very low temperatures (-200°C. or less) the junction maybe
calibrated in solid carbon dioxide (-78°C.) and liquid air (-184°C.).
Dewar has found that copper and German silver form a reliable junction
for very low temperatures, and the author has successfully used a
couple of Hoskin’s alloys for special work down to -200°C., a pivoted
indicator being employed. No couples tested show a linear relation
between E.M.F. and temperature at these low ranges.
Owing to the magnitude of the error caused by changes in the cold
junction, the thermo-electric method is not suited to the measurement
of atmospheric temperatures, or for explosive magazines or cold stores.
In such cases instruments of the resistance type, to be described
later, are used.
=Temperature of Steam, Exhaust Gases, etc.=—For measuring the
temperature of ordinary or superheated steam, the exhaust gases from
internal combustion engines, etc., iron-constantan junctions, with
suitable indicators, are satisfactory. When placed in a pipe the
junction should be as nearly as possible in the centre, so as to
avoid the cooling effect of the walls. Several junctions, situated in
different parts of the pipe, may be used with a single indicator and
suitable switchboard. The above remarks also apply to the hot-blast for
blast furnaces, and similar instances where the temperature does not
exceed 900° C.
=Measurement of Differences of Temperature.=—Cases frequently
arise in practice in which the difference in temperature between two
points is required, and if this difference be subject to rapid changes,
a mercury thermometer, from its large mass, would not respond with
sufficient rapidity to indicate these changes. In such cases a circuit
is made after the manner of fig. 2, one junction being located at
each point; thin wires of iron and constantan being used. For small
differences—1° C. or less—a mirror galvanometer should be used.
Calibration may be performed by placing one junction in hot water and
the other in cold, the water temperatures being read with an accurate
thermometer.
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