Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
=Relation between the Resistance of Platinum and Temperature.=—As
platinum is the only feasible metal to use in the construction of
resistance pyrometers, it is essential that the effect of temperature
on the resistance of this metal should be known. Difficulties were
experienced, in the early days of resistance pyrometers, from the fact
that different samples of platinum wire, of varying degrees of purity,
gave widely differing results in this connection; and no certainty was
attained until 1886, when Professor Callendar thoroughly investigated
the subject, and evolved a formula from which the temperature of a
given kind of platinum could be deduced with great accuracy from the
resistance. In order to understand this formula and its application, it
will be necessary to consider the underlying principles upon which it
is founded.
If the resistance of a platinum wire be measured at a number of
standard gas-scale temperatures, and the results depicted graphically
by plotting resistances against corresponding temperatures, the curve
obtained is part of a parabola, exhibiting a decrease in the rate at
which the resistance increases at the higher temperatures. A second
platinum wire, of different origin and purity, and of the same initial
resistance as the foregoing, would furnish a curve which, although
parabolic, would not overlap that obtained with the first wire. The
advance made by Callendar was to deduce a formula from which the
temperature of any kind of platinum wire could be deduced from its
resistance, after three measurements at known gas-scale temperatures
had been determined. The calibration of a resistance pyrometer was
thereby reduced to three exact observations, instead of a large number
distributed over the scale; and, moreover, the formula in question
was found to give results of great accuracy over a wide range of
temperature for any kind of platinum wire.
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