Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
Before dealing with Callendar’s formula, the term “degrees on the
platinum scale” will be explained. Such degrees are obtained by
assuming that the increase of resistance of platinum is uniform at
all temperatures; that is, that the temperature-resistance curve is a
straight line, and not a parabola. For example, a piece of platinum
wire of 2·6 ohms resistance at 0° C. will show an increase to 3·6 ohms
at 100° C.—an addition of 1 ohm for 100°. We now assume that a
further augmentation of 1 ohm, bringing the total to 4·6 ohms, will
represent an increase of 100°, or a temperature of 200°. Similarly,
a total resistance of 5·6 ohms would indicate 300°, and 12·6 ohms
1000°. The temperature scale obtained by this process of extrapolation
is called the “platinum scale,” and differs considerably from the
true or gas scale, the difference becoming greater as the temperature
rises. This is indicated in fig. 32, in which A represents the true
parabolic relation between resistance and temperature, and B the
assumed straight-line relation. Reading from curve A, the temperature
corresponding to 8 ohms resistance is 600° C.; but from B the same
resistance is seen to represent only 545° C., which is the “temperature
on the platinum scale” to which this resistance refers. An inspection
of fig. 32 shows that at all temperatures, except between 0° and 100°,
the platinum-scale readings for given resistances are less than those
indicated on the gas scale.
Callendar’s formula is expressed in terms of the difference between the
gas-scale and platinum-scale readings, and takes the form
_t_ - _p_ = δ{(_t_/100)^2 - (_t_/100)},
where _t_ = temperature on the gas scale,
_p_ = temperature on the platinum scale.
δ = a constant, depending upon the purity of
the wire.
[Illustration: FIG. 32.—CONNECTION BETWEEN RESISTANCE OF PLATINUM AND
TEMPERATURE: A, ON GAS SCALE; B, ON PLATINUM SCALE.]
In order to determine the value of δ, it is necessary to measure the
resistance of the wire at 0°, 100°, and a third temperature, which
should be considerably above 100°. The readings at 0° and 100° are
requisite to establish the platinum scale of temperatures; the third
reading is required to calculate the value of δ, as _p_ and _t_ are
equal at 0° and 100°, these points forming the basis of both scales. An
example is appended to make this matter clear.
_Example._—A platinum wire has a resistance in ice of 2·6
ohms; in steam, 3·6 ohms; in boiling sulphur, 6·815 ohms.
To find the value of δ, the boiling point of sulphur being
444·5 on the gas scale.
Since an increase of (3·6 - 2·6) = 1 ohm is produced by
100°, the increase observed in boiling sulphur,
(6·815 - 2·6) = 4·215 ohms, will represent a temperature,
on the platinum scale, of (4·215 × 100)/1 = 421·5° _p_.
Applying Callendar’s formula,
(444·5 - 421·5) = δ{(444·5/100)^2 - (444·5/100)}
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