Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
the value of δ is found to be 1·5.
Callendar, in his experiments, employed the boiling point of sulphur
for the third point, and determined this temperature on the gas scale
with great accuracy, The necessity for extreme precision in applying
this formula is made clear by noting the effects on the value of δ
resulting from small differences in the figures chosen in the above
example. If, for instance, the boiling point of sulphur on the gas
scale were taken at 2° lower, or 442·5, the value of δ would work out
to 1·37; and the error at 1200° C. thus caused would amount to 17°. The
same discrepancy would be observed if the resistance in boiling sulphur
were taken as 6·835 ohms, an error of 0·02 ohm; and a still greater
error would result if the difference in resistance at 0° and 100° were
measured as 0·99 ohm instead of 1 ohm. From an extensive experience of
the difficulties attendant on correctly determining the value of δ,
the author has found that no reliable result can be obtained unless
measuring instruments of the highest precision are used, and elaborate
precautions taken to ensure the exact correction for alterations in
the boiling points of water and sulphur occasioned by changes in
atmospheric pressure. Unless the necessary facilities are at hand, an
operator would be well advised to standardize a resistance pyrometer by
taking several fixed points and drawing a calibration curve, after the
manner recommended for a thermo-electric pyrometer.
If a resistance pyrometer be calibrated so as to read in platinum-scale
degrees, and the value of δ be known for the wire, the correct
gas-scale temperatures may be calculated from Callendar’s formula. The
table on next page gives the results of a number of calculations made
in this manner.
=Changes in Resistance of Platinum when constantly Heated.=—The
resistance of platinum undergoes a gradual change when the wire is kept
continuously above a red heat; and if the temperature exceed 1000° C.
the change becomes very marked after a time, leading to serious errors
in temperature indications when used in a pyrometer. The alteration
under notice is due, as shown by Sir William Crookes, to the fact that
platinum is distinctly volatile above 1000° C., and hence the diameter
of the wire diminishes. This variation constitutes a serious drawback
to the use of resistance pyrometers for temperatures exceeding 1000° C.
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