Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
an object such as a block of steel. It happens, therefore, that the
condition of perfect radiation is attained by the appliances in
everyday use; and, moreover, black-body radiations can always be
secured by placing a tube, closed at one end, in the heated space,
and receiving the radiations through the open end; for this again
represents an enclosure at a constant temperature. Similarly,
radiations from a solid in the interior of the tube of the electric
furnace shown in fig. 29 will be of the same description, and we can
therefore apply with accuracy any instrument based upon black-body
radiations, knowing that the same may be readily realised in practice.
The law connecting the energy radiated by a substance, under given
conditions, with its temperature, was variously stated by different
observers until Stefan, in 1879, deduced the true relation from certain
experimental data obtained by Tyndall. Stefan concluded that the
figures given by Tyndall indicated that the energy radiated by a given
solid varied as the fourth power of its absolute temperature. Numerous
experiments, under different conditions, showed that the fourth-power
law did not apply to all kinds of surfaces or circumstances; but a
strong confirmation of its truth when applied to black-body radiations
was forthcoming in 1884, when Boltzmann showed, from thermodynamic
considerations, that the quantity of energy radiated in a given time
from a perfect radiator must vary as the fourth power of its absolute
thermodynamic temperature. Certain assumptions made by Boltzmann in
this investigation were subsequently justified by experiment; and
numerous tests under black-body conditions have since amply verified
the law. It is upon the Stefan-Boltzmann law that radiation pyrometers
are based; the energy received by radiation from the heated substance,
under black-body conditions, being measured by the instrument, and
translated into corresponding temperatures on its scale.
Expressed in symbols, the fourth-power law takes the form—
E = K(T_{1}^4 - T_{2}^4),
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