Pyrotechnics: The History and Art of Firework MakingBrock, Alan St. H. (Alan St. Hill)
History
Pyrotechnics: The History and Art of Firework Making
Brock, Alan St. H. (Alan St. Hill)
Fireworks
Another source of accident of this class is the use of violence in
emergency with a composition which, although not sufficiently stable
for heavy charging, is quite safe for careful manipulation; as for
instance, where force is exerted to clear a funnel which has become
blocked with composition, or some similar action.
As regards the part played by heat in accidents of this class, a
study of the records clearly indicates how great is the influence of
weather. By far the greatest number of accidents take place in the
summer months; hot weather and a heavy atmosphere are the most likely
conditions to produce trouble for the pyrotechnist, although whether
the primary cause is heat or owing to an electrical condition of the
atmosphere it is difficult to say, probably it is the two conditions in
conjunction. Sulphur and shellac, two very important ingredients in the
art, are both capable of holding an electric charge, and it seems not
unlikely that they may be so charged in an electric atmosphere during
the process of mixing.
Accidents in Class II are generally less easily explained than those
in the former class and have occurred in many forms. As has been said,
during the period (about sixty-five years) from the introduction of
chlorate of potash to the Order in Council forbidding its use with
sulphur, numerous accidents occurred; spontaneous ignition, both whilst
drying during manufacture and even during mixing, ignition from very
slight friction, and for a time a frequent occurrence the detonation
of the contents of shell by the lifting charge. During the period
of seventeen years between the date of the Explosives Act and the
prohibition of chlorate sulphur mixture, twenty-eight accidents are
recorded, resulting in eleven deaths attributable to the use of such
mixtures.
The instability of chlorate sulphur compositions, however, does not
appear to be so much due to the presence of these two chemicals
themselves, but rather to the presence of impurity in conjunction with
them.
Commercial sulphur often contains free sulphurous acid, which acting
upon the chlorate produces chlorine tetroxide, which rapidly decomposes
and ignites the mass of the composition.
Other acids which produce decomposition of the chlorate are equally
likely to produce ignition. Of such cases, examples may be mentioned
of acid being present in the paste used for case and box-making, also
in gumwater which has been kept some time before using, and in starch
paste similarly treated. Spontaneous ignition has also been caused by
the contact of oil with finely divided carbon such as lampblack or
finely divided metals, such as magnesium and aluminium, which are so
largely used at the present time.
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