Pyrotechnics: The History and Art of Firework MakingBrock, Alan St. H. (Alan St. Hill)
History
Pyrotechnics: The History and Art of Firework Making
Brock, Alan St. H. (Alan St. Hill)
Fireworks
It is not meant to suggest that the impurities generally to be found in
bulk supplies are necessarily harmful to pyrotechnic results. This is
not so; salts give far better results in their natural or mineral form
than do those prepared synthetically. As an example of this saltpetre
may be cited. For pyrotechnic purposes the best obtainable is that from
Bengal, yet an analysis of this would probably be found to be less pure
than that synthetically prepared in Germany. But experiments have shown
that samples of the latter, taken from the same cask, but in different
parts, produce very distinctly varying results pyrotechnically.
Pyrotechny is an art, chemistry is a science, and although it is
impossible to deny that the former is greatly indebted to the latter
for the supply and production on a commercial scale of chemical
ingredients, yet it is possible to overestimate the position of
chemistry in the art, or possibly it might be more correct to say that
pyrotechny has its own chemistry.
Chemistry without pyrotechnic experience is apt to lead to erroneous
conclusions. To take a concrete instance: in an article in a famous
encyclopædia, obviously written by a chemist of standing, a portion
deals with the use of metal salts in the production of colour; the
writer gives copper as producing green, which no doubt it does in
the laboratory; in practice, however, copper is used solely for the
production of blue.
The question of purity in chemicals used in pyrotechny is a secondary
consideration, that is, of course, as long as the adulterants have no
adverse effect either as regards the pyrotechnic result or the safety
of the worker in manipulation. What is of first importance is its
pyrotechnic suitability, that is, it must produce the required result
and must be consistent. Unequal results are the bugbear of the firework
makers. As we have seen, constant experiments are necessary to keep an
even standard, but with irregularly functioning chemicals these would
be multiplied to an impossible degree.
The first group of compositions for consideration is that nearest
related to gunpowder, in fact, for the purposes of a work on
pyrotechny, gunpowder may be considered a particular case of this class.
The governing principle of this group, and one may say of all firework
compositions, is the same. For combustion to take place oxygen must be
present. When an inflammable article such as a piece of paper is set
on fire it takes up oxygen from the air. A pyrotechnic composition,
however, is so arranged that one of the ingredients has a supply of
oxygen which it is ready to give up; another, or others, are of a kind
ready to receive and combine with this oxygen.
The oxygen-supplying ingredient which is by far the most frequently
used is saltpetre, or, as it was formerly called, nitre, known
chemically as nitrate of potash.
Public-domain text, read in full here on John Shaqi.
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