Pyrotechnics: The History and Art of Firework MakingBrock, Alan St. H. (Alan St. Hill)
History
Pyrotechnics: The History and Art of Firework Making
Brock, Alan St. H. (Alan St. Hill)
Fireworks
Antimony, on account of its ready combustion, is more completely
consumed before leaving the case. In this connection it may be
mentioned that care is necessary in a mixture containing steel or iron
to avoid too large a proportion of the oxygen-bearing ingredient, for
fear of consuming it inside the case.
Another composition producing remarkable coruscations is the
old-fashioned “spur fire,” which consists of saltpetre, sulphur, and
lampblack. This composition requires very careful and experienced
mixing, or no effect will be produced, rendering its preparation a very
lengthy process.
This difficulty was somewhat overcome during the last century by the
addition of orpiment or sulphide of arsenic. Even with this addition,
however, its manufacture requires care and patience. It is a curious
fact that this composition, unlike most others, has the quality of
markedly improving by keeping. How the lampblack produces this unique
effect, or why its effect should be so different from that produced by
any other form of carbon, has not been satisfactorily explained.
The compositions we have been considering fall into one of two classes,
namely, those to produce force and those to produce sparks. These
two classes, with one other, namely that of colour, may be said to
include all the modern recreative firework compositions. Up to the
end of the eighteenth century the ingredients used in the production
of the compositions of these three classes were very few in number. A
considerably larger number went to supply the ingredients for a fourth
class now almost extinct, these might be called the flame-producing
class. The principle on which these compositions were designed was,
as it were, to overload a mixture of saltpetre and sulphur with
combustible material; this latter took the form of gums, resins, or
fats, the object being to produce a reddish or golden coloured flame.
The early writers give formulæ for variously coloured stars and fires,
which must have required considerable effort on the part of the
observer for identification. These belonged to the flame class.
Frézier, with more perception than most of the others, realised the
shortcomings of such compositions, merely designating them greenish
(_verdâtre_), yellowish, reddish, and russet. The only colour which
he professes to produce distinct is blue, which he obtained with pure
sulphur.
Progress from the earliest times of pyrotechny up to the first
quarter of the nineteenth century was very gradual and very slight.
The chemicals used by Bate and Babington in their actual pyrotechnic
compositions were as follows:—Gunpowder and its constituents, camphor,
pitch, resin, orpiment, linseed oil, both pure and boiled, oil of spike
(_spica lavandula_), oil of petre (rock oil), an oil known either as
benedict or tile, varnish (probably amber), iron scales, and aqua vitæ
(spirits of wine).
[Illustration: Diagram Illustrating the evolution of Pyrotechnic
Composition.]
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