MM. Curie and Laborde have recently discovered that _the salts of radium
are the source of a spontaneous and continuous evolution of heat_. This
evolution has the effect of keeping the salts of radium at a temperature
higher than that of their surroundings; an excess of temperature of 1·5°
has been observed. This excess of temperature is dependent upon the
thermal insulation of the body. MM. Curie and Laborde have determined
the amount of heat produced in the case of radium. They found that the
output is of the order of magnitude of 100 calories per grm. of radium
per hour. One grm.-atom (225 grm.) of radium give rise in one hour to
22,500 cal., a quantity of heat comparable to that produced by the
combustion of 1 grm.-atom (1 grm.) of hydrogen. So great an evolution of
heat can be explained by no ordinary chemical reaction, more
particularly as the condition of the radium remains unaffected for
years. The evolution of heat might be attributed to a slow
transformation of the radium atom. If this were the case, we should be
led to conclude that the quantities of energy generated during the
formation and transformation of the atoms are considerable, and that
they exceed all that is so far known.
_Chemical Effects produced by the New Radio-active Bodies._
_Colourations._—The radiations of strongly radio-active bodies are
capable of causing certain chemical reactions. The rays emitted by
radium products exercise colouring actions upon glass and porcelain.
The colouration of glass, generally brown or violet, is very deep; it is
produced in the body of the glass, and remains after removal of the
radium. All glasses become coloured after a longer or a shorter interval
of time, and the presence of lead is not essential. This fact may be
compared to that recently observed of the colouration of the glass of
vacuum tubes, after having been long in use for the production of
Röntgen rays.
M. Giesel has demonstrated that the crystallised halogen salts of the
alkali metals become coloured under the influence of radium, as under
the action of cathode rays. M. Giesel points out that similar
colourations are obtained when the salts of the alkalis are exposed to
sodium vapour.
I investigated the colouration of a collection of glasses of known
composition, kindly lent me for the occasion by M. Le Chatelier. I
observed no great variety in the colouration. It is generally brown,
violet, yellow, or grey. It appears to be associated with the presence
of the alkali metals.
With the pure crystallised alkali salts more varied and more vivid
colours are obtained; the salt, originally white, becomes blue, green,
yellow, brown, &c.
M. Becquerel has discovered that yellow phosphorus is transformed into
the red variety by the action of radium.
Paper is changed and coloured by the action of radium. It becomes
brittle, scorched, and, finally, resembles a colander perforated with
holes.
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