Since the beginning of our researches, M. Curie and I have, by heating
pitchblende, extracted a strongly radio-active gas, but, as in the
preceding experiment, the activity of this gas finally completely
vanished.
We could discern no new ray in the spectrum of this gas; this was
therefore not a case of a new radio-active gas, and we understood later
that it was the phenomenon of induced radio-activity.
Thus, for thorium, radium, and actinium induced radio-activity is
progressively propagated through the gases, from the radiating body to
the walls of the enclosure containing it, and the exciting principle is
carried away with the gas itself, when the latter is extracted from the
enclosure.
When the radio-activity of radium compounds is measured by the
electrical method by means of the apparatus of Fig. 1, the air between
the plates is itself radio-active; however, on passing a current of air
between the plates, there is no observable lowering of the intensity of
the current, which proves that the radio-activity distributed in the
space between the plates is of little account in comparison with that of
the radium itself in the solid state.
It is quite otherwise with thorium. The irregularities which I observed
in determining the radio-activity of the thorium compounds arose from
the fact that at this point I was working with a condenser open to the
air; the least air current caused a considerable change in the intensity
of the current, because the radio-activity dispersed in the space in the
vicinity of the thorium is considerable as compared with the
radio-activity of the substance.
This effect is still more marked in the case of actinium. A very active
compound of actinium appears much less active when a current of air is
passed over the substance.
The radio-active energy is therefore contained in the gas in a special
form. Mr. Rutherford suggests that radio-active bodies generate an
_emanation_ or gaseous material which carries the radio-activity. In the
opinion of M. Curie and myself, the generation of a gas by radium is a
supposition which is not so far justified. We consider the emanation as
radio-active energy stored up in the gas in a form hitherto unknown.
_Dissipation in Free Air of the Induced Activity of Solid Bodies._
A solid body, which has been excited by radium in an enclosed space for
a sufficient length of time, and which has then been removed from the
enclosure, parts with its activity in free air according to an
exponential law, which is the same for all bodies represented by the
following formula:—
I = I_{0}(_a__e_^{–_t_/θ_{1}} – (_a_ – 1)_e_^{–_t_/θ_{2}}).
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