_Theory of Interpretation of the Causes of Variations of Activity of
Radium Salts after Solution and after Heating._
The facts previously indicated may be in part explained by the theory
according to which the energy of radium is produced in the form of an
emanation, which is then transformed into the energy of radiation. When
a radium salt is dissolved, the emanation produced by it spreads beyond
the solution, and causes radio-activity outside the source from which it
proceeds; when the solution is evaporated, the solid salt obtained is
but slightly active, because it contains only a small amount of
emanation. Gradually the emanation is accumulated in the salt, the
activity of which rises to a limiting value, which is reached when the
production of the emanation by the radium compensates the loss by
external emission and by local transformation into Becquerel rays.
When a radium salt is heated, the external emission of the emanation is
greatly increased, and the phenomena of induced radio-activity are more
intense than when the salt is at the ordinary temperature. But when the
salt returns to the ordinary temperature it is exhausted, as is the case
after being dissolved, and contains but a small amount of emanation, its
activity having become greatly reduced. Gradually the emanation
accumulates afresh in the solid salt, and the radiation increases.
It may be said that radium gives rise to a constant generation of any
emanation—part of which escapes to the exterior, the remainder being
transformed in the radium itself into Becquerel rays. When radium is
raised to a red heat, it loses the greater part of its capacity to cause
the induction of activity; otherwise stated, the evolution of the
emanation is lessened. Consequently, the proportion of the emanation
utilised in the radium itself should be greater, and the substance
attains a higher limit of radio-activity.
We will endeavour to establish theoretically the law of rise of activity
of a solid radium salt which has been dissolved or has been heated. We
will assume that the intensity of radiation of radium is, at each
instant, proportional to the quantity of emanation, _q_, present in the
radium. We know that the emanation is spontaneously destroyed according
to a law such that, at each instant—
_q_ = _q__{0}_e_^{–_t_/θ} . . . . . . . . . 1,
_q__{0} being the amount of the emanation at the moment of starting the
observation, and θ the time constant, equal to 4·97 × 10^5 secs.
Now let Δ be the evolution of the emanation by radium, a quantity which
I will assume constant. Let us consider what would occur if no emanation
were escaping to the exterior. The emanation generated would then be
completely utilised by the radium for the production of the radiation.
We have from Formula 1—
_dq_/_dt_ = –(_q__{0}/θ)_e_^{–_t_/θ} = –_q_/θ;
and consequently, in the state of equilibrium, the radium would contain
a certain quantity of emanation, Q, such that—
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