Hardy and Miss Willcock[215] found that a solution of iodoform in
chloroform turned purple after exposure for 5 minutes to the rays from 5
milligrams of radium bromide. This action is due to the liberation of
iodine. By testing the effect of screens of different thicknesses, over
the radium, this action was found to be mainly due to the β rays from
the radium. Röntgen rays produce a similar coloration.
Hardy[216] also observed an action of the radium rays on the coagulation
of globulin. Two solutions of globulin from ox serum were used, one made
electro-positive by adding acetic acid, and the other electro-negative
by adding ammonia. When the globulin was exposed close to the radium in
naked drops, the opalescence of the electro-positive solution rapidly
diminished, showing that the solution became more complete. The
electro-negative solution was rapidly turned to a jelly and became
opaque. These actions were found to be due to the α rays of radium
alone.
This is further evidence in favour of the view that the α rays consist
of projected positively charged bodies of atomic dimensions, for a
similar coagulation effect is produced by the metallic ions of liquid
electrolytes, and has been shown by W. C. D. Whetham[217] to be due to
the electric charges carried by the ions.
=124. Gases evolved from radium.= Curie and Debierne[218] observed that
radium preparations placed in a vacuum tube continually lowered the
vacuum. The gas evolved was always accompanied by the emanation, but no
new lines were observed in its spectrum. Giesel[219] has observed a
similar evolution of gas from solutions of radium bromide. Giesel
forwarded some active material to Runge and Bödlander, in order that
they might test the gas spectroscopically. From 1 gram of a 5 per cent.
radium preparation they obtained 3·5 c.c. of gas in 16 days. This gas
was found, however, to be mainly hydrogen, with 12 per cent. of oxygen.
In later experiments Ramsay and Soddy[220] found that 50 milligrams of
radium bromide evolved gases at the rate of about 0·5 c.c. per day. This
is a rate of evolution about twice that observed by Runge and Bödlander.
On analysing the gases about 28·9 per cent. consisted of oxygen, and the
rest hydrogen. The slight excess of hydrogen over that attained in the
decomposition of water, they consider to be due to the action of oxygen
on the grease of the stop-cocks. The radio-active emanation from radium
has a strong oxidizing action and rapidly produces carbon dioxide, if
carbonaceous matter is present. The production of gas is probably due to
the action of the radiations in decomposing water. The amount of energy
required to produce the rate of decomposition observed by Ramsay and
Soddy—about 10 c.c. per day for 1 gram of radium bromide—corresponds to
about 30 gram-calories per day. This amount of energy is about two per
cent. of the total energy emitted in the form of heat.
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