=128. Thorium X.= Rutherford and Soddy[227], working with thorium
compounds, found that an intensely active constituent could be separated
from thorium by a single chemical operation. If ammonia is added to a
thorium solution, the thorium is precipitated, but a large amount of the
activity is left behind in the filtrate, which is chemically free from
thorium. This filtrate was evaporated to dryness, and the ammonium salts
driven off by ignition. A small residue was obtained which, weight for
weight, was in some cases several thousand times more active than the
thorium from which it was obtained, while the activity of the
precipitated thorium was reduced to less than one half of its original
value. This active constituent was named Th X from analogy to Crookes’
Ur X.
The active residue was found to consist mainly of impurities from the
thorium; the Th X could not be examined chemically, and probably was
present only in minute quantity. It was also found that an active
constituent could be partly separated from thorium oxide by shaking it
with water for some time. On filtering the water, and evaporating down,
a very active residue was obtained which was analogous in all respects
to Th X.
On examining the products a month later, it was found that the _Th X was
no longer active, while the thorium had completely regained its
activity_. A long series of measurements was then undertaken to examine
the time-rate of these processes of decay and recovery of activity.
[Illustration: Fig. 47.]
The results are shown graphically in Fig. 47, where the final activity
of the thorium and the initial activity of the Th X are in each case
taken as 100. The ordinates represent the activities determined by means
of the ionization current, and the abscissae represent the time in days.
It will be observed that both curves are irregular for the first two
days. The activity of the Th X increased at first, while the activity of
the thorium diminished. Disregarding these initial irregularities of the
curves, which will be explained in detail in section 208, it will be
seen that, after the first two days, the time taken for the thorium to
recover half its lost activity is about equal to the time taken by the
Th X to lose half its activity. This time in each case is about four
days. The percentage proportion of the activity regained by the thorium,
over any given interval, is approximately equal to the percentage
proportion of the activity lost by the Th X during the same interval.
[Illustration: Fig. 48.]
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